Форма хемосорбционного связывания золота(iii) из растворов ди-изо-бутилдитиокарбаматом таллия(I): супрамолекулярная структура и термическое поведение полимерного комплекса золота(III)-таллия(III) состава ([Au{S2CN(изо-C4H9)2}2][TlCl4])n

Иванов, А. В.; Бредюк, О. А.; Лосева, О. В.; Родина, Татьяна А.

doi:10.7868/s0132344x15020024

Координац. химия

2015

DOI: 10.7868/s0132344x15020024

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Форма хемосорбционного связывания золота(iii) из растворов ди-изо-бутилдитиокарбаматом таллия(I): супрамолекулярная структура и термическое поведение полимерного комплекса золота(III)-таллия(III) состава ([Au{S₂CN(изо-C₄H₉)₂}₂][TlC_l4])_n

А. В. Иванов¹,

О. А. Бредюк²,

О. В. Лосева³

et al.

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Double pseudo-polymeric complexes of [Au(S2CNR2)2][TlCl4], R2 = (CH2)5, (CH2)6: preparation, structural organization, and thermal behavior (low-temperature reduction and crystallization of gold)

Bredyuk,

Loseva,

Rodina

et al. 2023

Žurnal obŝej himii

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The capability of thallium(I) alkylenedithiocarbamates to bind gold(III) from solutions in 2 M HCl was studied. Double complexes of [Au{S2CN(CH2)5}2][TlCl4] and [Au{S2CN(CH2)6}2][TlCl4] were preparatively isolated as individual forms of gold(III) binding into the solid phase. In the crystalline state, the ionic structural units of the complexes are combined together due to the secondary Au···S, Tl···S and S···Cl bonds that results in complicated supramolecular architectures. Thermal behavior of compounds was studied using the simultaneous thermal analysis technique; both reduced elemental gold and thallium(I) chloride were identified as the final thermolysis products.

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Double pseudo-polymeric complexes of [Au(S2CNR2)2][TlCl4], R2 = (CH2)5, (CH2)6: preparation, structural organization, and thermal behavior (low-temperature reduction and crystallization of gold)

Bredyuk,

Loseva,

Rodina

et al. 2023

Žurnal obŝej himii

View full text Add to dashboard Cite

show abstract

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Double pseudo-polymeric complexes of [Au(S2CNR2)2][TlCl4], R2 = (CH2)5, (CH2)6: preparation, structural organization, and thermal behavior (low-temperature reduction and crystallization of gold)

Double pseudo-polymeric complexes of [Au(S2CNR2)2][TlCl4], R2 = (CH2)5, (CH2)6: preparation, structural organization, and thermal behavior (low-temperature reduction and crystallization of gold)

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