СИНТЕЗ 3-Гидроксиадамантан-1-Илметанолов, "Журнал Органической Химии"

Ивлева, Е.А.; Погуляйко, А.В.; Климочкин, Ю. Н.

doi:10.7868/s0514749218090042

Журнал органической химии

2018

DOI: 10.7868/s0514749218090042

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СИНТЕЗ 3-Гидроксиадамантан-1-Илметанолов, "Журнал Органической Химии"

Е.А. Ивлева¹,

А.В. Погуляйко²,

Ю. Н. Климочкин³

Abstract: Разработан удобный метод получения 3-гидроксиадамантан-1-илметанолов, основанный на последовательном нитроксилировании адамантан-1 -илметанолов в дымящей азотной кислоте и восстановлении промежуточных нитроэфиров гидразингидратом. Диолы получены также восстановлением 3-нитрокси-1-нитроксиметиладамантанов. Наряду со спиртами образуются замещенные адамантан-1-карбоновые кислоты.

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2023

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Synthesis and chemical transformations of 1-aryladamantanes

Ivleva,

Orlinsky,

Zaborskaya

et al. 2023

Žurnal organičeskoj himii

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The synthesis was carried out and the transformations of 1-aryladamantanes in fuming nitric acid were studied. The reactions include nitroxylation of saturated cage and nitration of the aromatic moiety and lead to 3-(dinitroaryl)-1-adamantylnitrates. A number of new polyfunctional compounds have been synthesized based on reactions of substituted 3-(dinitroaryl)-1-adamantyl nitrates with nucleophiles in concentrated sulfuric acid. Due to the multifunctionality, the obtained compounds can be used as starting materials in the synthesis of substances with a wide spectrum of biological activity and materials with a complex of valuable properties.

show abstract

Synthesis and chemical transformations of 1-aryladamantanes

Ivleva,

Orlinsky,

Zaborskaya

et al. 2023

Žurnal organičeskoj himii

View full text Add to dashboard Cite

show abstract

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СИНТЕЗ 3-Гидроксиадамантан-1-Илметанолов, "Журнал Органической Химии"

Cited by 1 publication

References 48 publications

Synthesis and chemical transformations of 1-aryladamantanes

Synthesis and chemical transformations of 1-aryladamantanes

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