(μ-Di-<i>tert</i>-butylsilanediolato)bis[bis(η<sup>5</sup>-cyclopentadienyl)methylzirconium]

Berg, David J.; Gajecki, Leah; Hill, Hunter; Twamley, Brendan

doi:10.1107/s2056989019014762

Acta Cryst E

2019

DOI: 10.1107/s2056989019014762

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(μ-Di-tert-butylsilanediolato)bis[bis(η⁵-cyclopentadienyl)methylzirconium]

David J. Berg

Leah Gajecki

Hunter Hill

et al.

Abstract: The reaction of t-Bu2Si(OH)2 with two equivalents of Cp2Zr(CH3)2 produces the t-Bu2SiO2-siloxide bridged dimer where one methyl group is retained per zirconium atom. The retention of one methyl group per metal center affords a site for further reactivity.

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(μ-Di-tert-butylsilanediolato)bis[bis(η⁵-cyclopentadienyl)methylzirconium]

Abstract: The reaction of t-Bu2Si(OH)2 with two equivalents of Cp2Zr(CH3)2 produces the t-Bu2SiO2-siloxide bridged dimer where one methyl group is retained per zirconium atom. The retention of one methyl group per metal center affords a site for further reactivity.

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References 78 publications

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(μ-Di-tert-butylsilanediolato)bis[bis(η5-cyclopentadienyl)methylzirconium]

Abstract: The reaction of t-Bu2Si(OH)2 with two equivalents of Cp2Zr(CH3)2 produces the t-Bu2SiO2-siloxide bridged dimer where one methyl group is retained per zirconium atom. The retention of one methyl group per metal center affords a site for further reactivity.

Cited by 0 publications

References 78 publications

No citations

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(μ-Di-tert-butylsilanediolato)bis[bis(η⁵-cyclopentadienyl)methylzirconium]