μ-Alkyne dicobalt hexacarbonyl complexes of conjugated enynes as substrates in the arylthio-mediated stepwise AdE reactions

Lazareva, M. I.; Nguyen, Son Truong; Nguyen, Minh; Emiru, Hilina; McGrath, Nick A.; Caple, R.; Smit, W. A.

doi:10.1070/mc2001v011n06abeh001527

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Propargylic Coupling Reactions via Bimetallic Alkyne Complexes: The Nicholas Reaction

Green

Nicholas

2020

Organic Reactions

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The hexacarbonyldicobalt complexes of propargylic cations are generated readily, predominantly from alkynedicobalt complexes bearing propargylic leaving groups. These cations have both good stability and reactivity, and enter into reaction with a wide range of carbon‐ and heteroatom‐based nucleophiles in a reliable manner; these are widely known as Nicholas reactions. In conjunction with the ready incorporation and removal of the dicobalt unit, these reactions have been employed extensively in total synthesis.

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Propargylic Coupling Reactions via Bimetallic Alkyne Complexes: The Nicholas Reaction

Green

Nicholas

2020

Organic Reactions

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ChemInform Abstract: μ‐Alkyne Dicobalt Hexacarbonyl Complexes of Conjugated Enynes as Substrates in the Arylthio‐Mediated Stepwise Ad_E Reactions.

Lazareva

Nguyen

et al. 2002

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Elaboration of a Lewis acid-free protocol for the alkylation of silicon-containing π-donors by β-arylthioalkyl chlorides

Ratnikov¹,

Tumanov²,

Smit³

2010

Tetrahedron

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μ-Alkyne dicobalt hexacarbonyl complexes of conjugated enynes as substrates in the arylthio-mediated stepwise AdE reactions

Cited by 3 publications

References 13 publications

Propargylic Coupling Reactions via Bimetallic Alkyne Complexes: The Nicholas Reaction

Propargylic Coupling Reactions via Bimetallic Alkyne Complexes: The Nicholas Reaction

ChemInform Abstract: μ‐Alkyne Dicobalt Hexacarbonyl Complexes of Conjugated Enynes as Substrates in the Arylthio‐Mediated Stepwise Ad_E Reactions.

Elaboration of a Lewis acid-free protocol for the alkylation of silicon-containing π-donors by β-arylthioalkyl chlorides

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μ-Alkyne dicobalt hexacarbonyl complexes of conjugated enynes as substrates in the arylthio-mediated stepwise AdE reactions

Cited by 3 publications

References 13 publications

Propargylic Coupling Reactions via Bimetallic Alkyne Complexes: The Nicholas Reaction

Propargylic Coupling Reactions via Bimetallic Alkyne Complexes: The Nicholas Reaction

ChemInform Abstract: μ‐Alkyne Dicobalt Hexacarbonyl Complexes of Conjugated Enynes as Substrates in the Arylthio‐Mediated Stepwise AdE Reactions.

Elaboration of a Lewis acid-free protocol for the alkylation of silicon-containing π-donors by β-arylthioalkyl chlorides

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Product

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ChemInform Abstract: μ‐Alkyne Dicobalt Hexacarbonyl Complexes of Conjugated Enynes as Substrates in the Arylthio‐Mediated Stepwise Ad_E Reactions.