γ-Amino Alcohols via Energy Transfer Enabled Brook Rearrangement
Ranjini Laskar,
Subhabrata Dutta,
Jan C. Spies
et al.
Abstract:In the long-standing quest to synthesize fundamental building blocks with key functional group motifs, photochemistry in the recent past has comprehensively established its attractiveness. Amino alcohols are not only functionally diverse but are ubiquitous in the biologically active realm of compounds. We developed bench-stable bifunctional reagents that could then access the sparsely reported γ-amino alcohols directly from feedstock alkenes through energy transfer (EnT) photocatalysis. A designed 1,3-linkage … Show more
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