Composites were obtained in the in SiC-SiAlON and Al 2 O 3 -SiAlON system. Physical-chemical processes going on at the obtaining of SiALON within the range of 800˚C -1500˚C were studied. Charge compositions and sintering regime were selected. It was proved that X-SiALON was obtained at the sintering of kaolin-aluminum powder at 1500˚C, while β-SiALON was formed at the sintering of SiC-Aluminum powder, silicium and Al 2 O 3 -aluminum powder, silicium at 1500˚C. Corrosion properties of the materials were studied. Investigations were performed by the methods of X-Ray structural and microscopical analysis.