2009
DOI: 10.1016/j.apcatb.2008.07.007
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β-MnO2 nanowires: A novel ozonation catalyst for water treatment

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Cited by 134 publications
(56 citation statements)
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“…In recent years, heterogeneous catalytic ozonation studies mainly focused on increasing ozone mass transfer and amount of • OH generation. Heterogeneous catalysts commonly used for this process include activated carbon [3][4][5], metal oxides [2,[6][7][8][9][10][11][12], and metals on supports [13][14][15][16][17][18][19]. However, industrial-scale application of these materials is inhibited by their complex separation, low mechanical strength, high cost, or easy oxidation.…”
Section: Introductionmentioning
confidence: 99%
“…In recent years, heterogeneous catalytic ozonation studies mainly focused on increasing ozone mass transfer and amount of • OH generation. Heterogeneous catalysts commonly used for this process include activated carbon [3][4][5], metal oxides [2,[6][7][8][9][10][11][12], and metals on supports [13][14][15][16][17][18][19]. However, industrial-scale application of these materials is inhibited by their complex separation, low mechanical strength, high cost, or easy oxidation.…”
Section: Introductionmentioning
confidence: 99%
“…More recently, metal and metal oxides nanoparticles have proved to be promising catalysts for ozone decomposition, owing to their high surface specific area and a high number of surface-exposed atoms [10][11][12][13][14][15][16]. These nanoparticles are usually deposited on a support to facilitate their recovery and finally to increase their durability.…”
Section: Introductionmentioning
confidence: 99%
“…Heterogeneous catalytic ozonation, which is one of the most attractive alternatives, aims to enhance removal of more refractory compounds through the transformation of ozone into more reactive species and/ or through adsorption and reaction of the pollutants on the surface of the catalyst. Oxides of transition metals, such as manganese [11][12][13][14], titanium [4,5] or cobalt [15,16], are amongst the most frequently studied ozonation catalysts. It has been proven by many authors that activated carbon can act initiating the ozone decomposition [1,[17][18][19], leading to the formation of oxygenated active species that are responsible for enhancing the mineralization of organic compounds.…”
Section: Introductionmentioning
confidence: 99%