α-Substituted phthalocyanines based on metal-induced H- or J-type aggregation for silver and palladium ions: synthesis, fluorescence, and antimicrobial and antioxidant properties

Abstract

In this study, firstly, 3-(2,3-bis(hexadecylthio)propoxy)phthalonitrile (2) as a new phthalonitrile derivative was prepared. Then, new types of non-peripheral phthalocyanine derivatives [CuPc (3), ZnPc(4), and CoPc(5)] were synthesized by using this...

Novel axially symmetric and unsymmetric silicon(iv) phthalocyanines having anti-inflammatory groups: synthesis, characterization and their biological properties

“…Recently the number of studies on the biological chemistry and biological activity of metal-containing agents has been going up since there is increasing demand for more effective agents in medicine and healthcare. 1,2 Metal complexes have a major impact on treating disease due to their spectral and magnetic properties and their interaction with many substances in biological systems. 1 Therefore, synthesizing novel metal-containing compounds and investigating their biological activities are important for explaining the mechanisms of metal-containing compounds found in living organisms.…”

“…Among these complexes, metalleted Pc derivatives in particular have been extensively studied as antioxidant agents. 2,12,[15][16][17][18][19][20][21][22] Multidrug resistance of human pathogenic bacteria to commercial anti-microbial drugs has led to the investigation of more effective alternative molecules like metal complex derivatives. 23 In recent years, studies on the antimicrobial 10,17,[24][25][26][27][28][29][30] and antimicrobial PDT (aPDT) properties of Pc derivatives have been increasing.…”

Synthesis of (4R)‐2‐(3‐hydroxyphenyl)thiazolidine‐4‐carboxylic acid substituted phthalocyanines: Anticancer activity on different cancer cell lines and molecular docking studies

“…One of the promising molecules in this field are phthalocyanine compounds due to capable of mimicking the properties of biologically important molecules such as chlorophyll and hemoglobin. [ 3 ]…”

Synthesis and Characterization of Zinc (II) Phthalocyanine for Screening Potential Solar Cell Dye Application

“…Herein, we shall investigate the tetranitro Zinc Phthalocyanine variation. Assessing how the tetranitro Zinc structural variations, influence the organic semiconducting dyes aggregation [7,9]. Comparing UV-Vis data against DFT computed data, allowing the type of aggregation occurring between the two tetranitro Zinc Phthalocyanine variation molecules to be deduced as well as supporting the theorised cause of aggregation-caused quenching theory.…”