α-(4-Nitrocyclohexyl)-ι-nitropoly(azo-1,4-cyclohexylene N,N'-dioxide), an Oligomeric Nitrosoalkane, Exemplifying a Novel Potential Catenation System

Childress, William L.; Donaruma, L. Guy

doi:10.1021/ma60040a006

Cited by 6 publications

(4 citation statements)

References 4 publications

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“…The high degree of polymerization for the p-and m-dinitrosobenzenes is in marked contrast to the values established by Donaruma and coworkers 90,91 for oligomeric 1,4dinitrosocyclohexanes for which the synthetic route involves reduction of 1,4-dinitrocyclohexane to the corresponding (10) dihydroxylamine, followed by mild oxidation to the dinitroso compound. It was shown that n 5 2 or 3 in the oligomeric product (26).…”

Section: Dinitroso Compounds With Intermolecular Interactionscontrasting

confidence: 73%

“…It was shown that n 5 2 or 3 in the oligomeric product (26). 90 The later paper reports the synthesis of two further oligomers (27); for the first of these, n 5 87 and for the second n 5 10-11. These are the only reported syntheses of polymers of dinitrosocyclohexanes, and it is important to extend knowledge of such compounds by using further structural techniques.…”

Section: Dinitroso Compounds With Intermolecular Interactionsmentioning

confidence: 99%

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Dinitroso and polynitroso compounds

Gowenlock

Richter‐Addo

2005

Chem. Soc. Rev.

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The growing interest in the chemistry of C-nitroso compounds (RN=O; R = alkyl or aryl group) is due in part to the recognition of their participation in various metabolic processes of nitrogen-containing compounds. C-Nitroso compounds have a rich organic chemistry in their own right, displaying interesting intra- and intermolecular dimerization processes and addition reactions with unsaturated compounds. In addition, they have a fascinating coordination chemistry. While most of the attention has been directed towards C-nitroso compounds containing a single -NO moiety, there is an emerging area of research dealing with dinitroso and polynitroso compounds. In this critical review, we present and discuss the synthetic routes and properties of these relatively unexplored dinitroso and polynitroso compounds, and suggest areas of further development involving these compounds. (126 references.).

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Section: Dinitroso Compounds With Intermolecular Interactionscontrasting

confidence: 73%

Section: Dinitroso Compounds With Intermolecular Interactionsmentioning

confidence: 99%

Dinitroso and polynitroso compounds

Gowenlock

Richter‐Addo

2005

Chem. Soc. Rev.

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“…Also the polymer shows no strong bands at 1530-1570 cm™1 for C-ÑO2 groups, in contrast to 1,4-dinitrosocyclohexane, which is oligomeric at room temperature with terminal nitro groups. 15 Thus the lack of terminal NO2 groups and also of residual NO groups in the infrared spectrum indicates that poly(l,4phenyleneazine N^V-dioxide) is a high molecular weight material.…”

Section: Resultsmentioning

confidence: 99%

Investigation of the polymerization of 1,4-dinitrosobenzene by low-temperature infrared and UV absorption spectroscopy

Hacker¹

1993

Macromolecules

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“…It was shown that n = 2 or 3 in the oligomeric product (26). 90 The later paper reports the synthesis of two further oligomers (27); for the first of these, n = 87 and for the second n = 10-11. These are the only reported syntheses of polymers of dinitrosocyclohexanes, and it is important to extend knowledge of such compounds by using further structural techniques.…”

Section: Dinitroso Compounds With Intermolecular Interactionsmentioning

confidence: 99%