Zwitterionic Poly(aryl ether ketone) with Water-Actuated, Reshaping-Reconfiguration Ability and Triple Shape Memory Effect

Yang, Shuai; He, Yang; Leng, Jinsong

doi:10.1021/acsapm.2c00245

Cited by 6 publications

(5 citation statements)

References 43 publications

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“…PAEK exhibited a high modulus of 2−2.5 GPa, but a relatively lower elongation at break of less than 4.5%, with the strength ranging from 30.4 to 45.6 MPa. Obviously, the mechanical properties of the shape memory PAEKs (σ = 25−70 MPa) were comparable to those reported, [19][20][21][22][23]25,26,33,55 suggesting that the addition of PEGDA and NVP did not significantly reduce the strength, and were much stronger than PEDGA/NVP hydrogels. 53 The cross-linker PEGDA400/PEGDA600 was pivotal in adjusting the mechanical properties.…”

Section: Mechanical Properties Of Paeksupporting

confidence: 77%

“…Leng et al achieved thermo- and electric-triggered PAEK with excellent solubility, adjustable transition temperature, and impressive shape memory properties by modulating the variation of bisphenol monomers. Furthermore, the multiple response shape memory effect and extended applications could be realized by incorporating inorganic fillers. − This chemically and physically modified approach greatly enriched the field of shape memory PAEK and demonstrated its potential application as a space-deployable structure, intelligent jet propulsion system, high-temperature sensor, and actuator. − …”

Section: Introductionmentioning

confidence: 99%

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Toward 4D Printing of Shape Memory Polymers Based on Polyaryletherketone/NVP/PEGDA through Molecular Engineering and Direct Ink Writing 3D Printing

Gao,

Gong,

Cao

et al. 2023

ACS Appl. Polym. Mater.

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Polyaryletherketone (PAEK), an engineering plastic with exceptional mechanical properties and a high glass transition temperature, can be tailored with various properties to meet the multiple requirements of aerospace applications. However, it remains a challenge to 3D print PAEK with good properties. Herein, a direct ink writing (DIW) 3D printable PAEK ink has been developed, and the yielded PAEK parts possess high tensile strength and excellent shape memory properties. The incorporation of N-vinyl-2-pyrrolidone (NVP) and polyethylene glycol diacrylate PEGDA into PAEK oligomers (PAEKOs) facilitated their versatility as diluents or reactive functional monomers. This characteristic enabled random cross-linking through photoinitiator exposure for the formation of block copolymers, establishing the essential stationary and reversible phases needed for shape memory capabilities. The photocured PAEK demonstrated excellent comprehension performances, including an outstanding tensile strength (42.6 MPa), thermal stability (T d -246 °C), shape fixation ratio (>93%), and shape recovery ratio (>100%). Furthermore, PAEK with a greater shape memory effect was utilized as an actuator to realize gripping and releasing at high temperatures (140 °C). This study therefore provides an emerging strategy to fabricate shape memory components for challenging environments using DIW technology. This approach also holds promise for implementation in systems beyond PAEK which have typically been difficult to print.

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Section: Mechanical Properties Of Paeksupporting

confidence: 77%

Section: Introductionmentioning

confidence: 99%

Toward 4D Printing of Shape Memory Polymers Based on Polyaryletherketone/NVP/PEGDA through Molecular Engineering and Direct Ink Writing 3D Printing

Gao,

Gong,

Cao

et al. 2023

ACS Appl. Polym. Mater.

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“…The complex formation brings severe challenges to conventional plugging materials and puts forward higher requirements for temperature resistance, compressive strength, and retention capacity of plugging materials 4–6 . For the development of lost circulation materials for high‐temperature gas wells, series of works have been developed, mainly focusing on gel and temperature‐sensitive shape memory materials 7–18 …”

Section: Introductionmentioning

confidence: 99%

“…[4][5][6] For the development of lost circulation materials for high-temperature gas wells, series of works have been developed, mainly focusing on gel and temperaturesensitive shape memory materials. [7][8][9][10][11][12][13][14][15][16][17][18] Bai et al [19][20][21] have developed a gel plugging material with temperature resistance up to 160 C based on the adhesive plugging characteristics. The storage modulus is up to 60 Pa. Mansour et al 22,23 first proposed the intelligent temperature-sensitive shape memory plugging material, which can expand under high-temperature environment, improve the plugging efficiency of fracture formation, and has a good wellbore strengthening effect.…”

Section: Introductionmentioning

confidence: 99%

Novel smart plugging material for high‐temperature gas well

Li¹,

Zhou

Liu³

2023

Polymer Engineering & Sci

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A novel smart material is developed, which is synthesized by succinic anhydride, epoxy resin, and zinc acetylacetone hydrate. The smart material has excellent properties of self‐healing, shape memory, and degradation. The experimental results of performance characterization show that the material has good thermal stability. The glass transition temperature is adjustable between 100 and 120°C, and the storage modulus can reach 20 GPa. The maximum thermal expansion at 50°C is less than 15%, the thermal expansion equilibrium time at 120°C is less than 5 min, and the maximum thermal expansion is 131%. The stress relaxation time at 120°C is more than 2 h, which can slowly self‐heal on the basis of maintaining the mechanical strength. When the NaOH content is 1.5%, the degradation equilibrium can be reached in about 3 h, and the maximum degradation rate is 86%. The comprehensive performance evaluation shows that after hot rolling at 120°C/16 h, the material has no effect on the rheology and filtration properties. When plugging the fracture width of 5 × 4 mm, the pressure bearing capacity reaches 10 MPa. Its main mechanism is temperature‐sensitive expansion, and the stress relaxation effect heals and blocks the micro pore throat.

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“…Shape memory polymers (SMPs) are a type of smart material that can change their shape in response to one or more stimuli, such as temperature, − light, − electricity, , magnetic field, − pH, , solvents, , water (moisture), − microwave, , and gases like carbon dioxide . Their unique properties have enabled a wide range of potential applications, including biomedical engineering, − aerospace materials, electronics, , and smart textiles .…”

Section: Introductionmentioning

confidence: 99%

Spine-Inspired Fabrication of Polynorbornene Copolymers with Multi-stimulus, Multiple Shape Memory, and Self-Healing Performances

Bai,

Li,

Yang

et al. 2023

ACS Appl. Polym. Mater.

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Multiple shape memory polymers (MSMPs), capable of remembering multiple temporary shapes in response to distinct stimuli, hold broad prospects for application. The design of MSMPs generally extends from the concept of dual shape memory polymers, yet innovating methods for their design and preparation remain challenging. In this work, we drew inspiration from the spine and developed an approach for the design and preparation of MSMPs. This approach employs intramolecular hydrogen bonds and resistance among semirigid chains to stabilize all the transition states in situ. The formation of metastable states was used to shape the memory design. Through this strategy, we have synthesized a series of polynorbornene copolymers PNB-mSi-nAc-DCPD (m/n = 3/1, 1/1, or 1/3) with dual-and triple-shape memory effect when subjected to stimuli such as thermal, alcohol/ water, and pH. Furthermore, these copolymers demonstrate superior self-healing, mechanical, and easy processing performance, markedly broadening their potential applications.

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Zwitterionic Poly(aryl ether ketone) with Water-Actuated, Reshaping-Reconfiguration Ability and Triple Shape Memory Effect

Cited by 6 publications

References 43 publications

Toward 4D Printing of Shape Memory Polymers Based on Polyaryletherketone/NVP/PEGDA through Molecular Engineering and Direct Ink Writing 3D Printing

Toward 4D Printing of Shape Memory Polymers Based on Polyaryletherketone/NVP/PEGDA through Molecular Engineering and Direct Ink Writing 3D Printing

Novel smart plugging material for high‐temperature gas well

Spine-Inspired Fabrication of Polynorbornene Copolymers with Multi-stimulus, Multiple Shape Memory, and Self-Healing Performances

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