Zur Reaktion von Silanolen mit Alkoholen

Kohlheim, I.; Lange, D.; Kelling, H.

doi:10.1002/prac.199633801125

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Cited by 7 publications

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“…In a great number of works reactivity data for silicon compounds have been correlated with Taft σ*-constants (see review, 10 and refrs. [21][22][23] ). However, the authors never paid attention to a close correlation between σ* and steric E s constants (R = 0.865, or without Me-group R = 0.950).…”

Section: Introductionmentioning

confidence: 99%

Steric effects of alkyl substituents in silicon chemistry

Ploom¹,

Panov²,

Tuulmets³

2006

Arkivoc

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Reactivity data for a number of reactions taking place at Si atoms in organosilicon compounds containing a variety of alkyl groups have been examined for statistical correlations with steric parameters. Four practically equivalent sets of parameters are now available for quantitative description of steric effects of alkyl substituents in organosilicon compounds. Alkyl substituents contribute to the reactivity exclusively with their steric effects. Steric effects in silicon compounds are additive.

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