Zur Kenntnis der Schwefel‐Blei‐Bindung

Bauer, Hugo; Burschkies, Karl

doi:10.1002/cber.19330660802

Cited by 10 publications

(5 citation statements)

References 3 publications

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“…19 Hexakis(p-tolyl)digermane. 81 1 H NMR (δ, ppm, CDCl 3 ): 7.20 (d, 12H, 3 J H−H = 7.8 Hz, Ar), 7.06 (d, 12H, 3 J H−H =7.8 Hz, Ar), 2.32 (s, 18H, CH 3 ). EI-MS m/z (%): 694 (6) [M] + , 347 (100) [M − (p-Tol) 3 Ge] + , 165 (19) [Ge(p-Tol)] + .…”

Section: ■ Experimental Sectionmentioning

confidence: 99%

“…Ph 3 GeNMe 2 , ( p -Tol) 3 GeNMe 2 , ( p -Tol) 3 GeH, [( p -Tol) 3 Ge] 2 , (Me 3 Si) 3 GeCeCl 3 ( 1 ), and [(Me 3 Si) 3 GeCl 2 ] 2 ( 2 ) were prepared according to published procedures. Improved protocols were used for the synthesis of (C 6 F 5 ) 3 GeCl, (C 6 F 5 ) 2 GeBr 2 , (C 6 F 5 ) 3 GeH, and (C 6 F 5 ) 2 GeH 2 …”

Section: Experimental Sectionmentioning

confidence: 99%

“…76 The aromatic rings adopt staggered conformations with the values of torsion angles C−Ge−Ge−C between 38. 81 Tol) 3 Ge] 2 Ge(p-Tol) 2 (2.4450 and 2.4359 Å) 49 (Table 3). Similar to the case for compound 5, this elongation is probably caused by the effects of electron-withdrawing C 6 F 5 groups.…”

Section: ■ Introductionmentioning

confidence: 99%

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“Donor–Acceptor” Oligogermanes: Synthesis, Structure, and Electronic Properties

et al. 2013

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A series of oligogermanes, (Me 3 Si) 3 GeGeCl 3 , (C 6 F 5 ) 3 GeGePh 3 , (C 6 F 5 ) 3 GeGe(p-Tol) 3 , and (C 6 F 5 ) 2 Ge[Ge(p-Tol) 3 ] 2 , containing substituents with different electronic properties at neighboring germanium atoms were synthesized. According to X-ray diffraction studies, UV/visible spectroscopy, and quantum chemical calculations, these "donor−acceptor" oligogermanes are characterized by energies of electronic transitions lower than those for other similar compounds.

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Section: ■ Experimental Sectionmentioning

confidence: 99%

Section: Experimental Sectionmentioning

confidence: 99%

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“Donor–Acceptor” Oligogermanes: Synthesis, Structure, and Electronic Properties

et al. 2013

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“…--/ - A number of metallic derivatives of thioglycolic and various other sulfhydrylcarboxylic acids are known in which the organic acid functions dibasically, for example, the lead salts of -sulfhydrylpropionic acid (12), /5-sulfhydrylpropionic acid (122), and o-sulfhydrylpropionic acid (12) The coordination sphere of the lead atom does not appear to be filled in these cases.…”

Section: B the Bidentate Compoundsmentioning

confidence: 99%

“…Glutamic acid, HOOCCH2CH2CHNH2COOH, forms copper compounds similar to those of aspartic acid (202). The lead (12,122) and cobalt (236) derivatives are probably tridentate compounds of this class.…”

Section: C2hb-c-c-chsmentioning

confidence: 99%