Zur Kenntnis der „oxydierenden”︁ Wirkungen der Alkalien, II. Mitteilung: Aromatische Oxy‐aldehyde

Lock, Gunther

doi:10.1002/cber.19290620512

Cited by 24 publications

(3 citation statements)

References 18 publications

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“…The solvent was removed on a rotary evaporator to give a brown solid which was recrystallized from hexane and ether to give light brown crystals (36.22 g, 73%). mp 130 °C, lit . mp 134 °C.…”

Section: Methodsmentioning

confidence: 99%

Preparation of 2,8-Dihydroxy-5,6,11,12-Tetrahydro-5,11- epoxydibenzo[a,e]cycloctene, an Analogue of Kagan's Ether

Harmata

Kahraman

1999

J. Org. Chem.

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Section: Methodsmentioning

confidence: 99%

Preparation of 2,8-Dihydroxy-5,6,11,12-Tetrahydro-5,11- epoxydibenzo[a,e]cycloctene, an Analogue of Kagan's Ether

Harmata

Kahraman

1999

J. Org. Chem.

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“…Hot alkali, especially in the presence of air, has a strong oxidizing action (85) and traces of hydroxy acids are sometimes encountered (24). 3. Triphenylmethane "resins"…”

Section: Hydroxy Acidsmentioning

confidence: 99%

“…The Cannizzaro reaction of aromatic aldehydes with alkali is reported to fail with 0-and p-hydroxyaldehydes (85). It appears likely that other condensations of well-established precedence (107,136) There is no report of the isolation of this type of compound or its hydrolysis product from a Reimer-Tiemann reaction.…”

Section: Ring-expansion Productsmentioning

confidence: 99%

The Reimer-Tiemann Reaction.

Wynberg¹

1960

Chem. Rev.

195

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TheCannizzaro Reaction

Geissman

2011

Organic Reactions

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The reaction in which two aldehyde groups are transformed into the corresponding hydroxyl and carbonyl functions, existing separately or in combination as an ester, has been termed the Cannizzaro reaction. Here the discussion is restricted to the dismutation of two similar aldehyde groups into the corresponding alcohol and carboxylic salt function by means of aqueous or alcoholic and alkali. The conversion of benzaldehyde into a mixture of benzyl alcohol and sodium benzoate is an example.

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Zur Kenntnis der „oxydierenden”︁ Wirkungen der Alkalien, II. Mitteilung: Aromatische Oxy‐aldehyde

Cited by 24 publications

References 18 publications

Preparation of 2,8-Dihydroxy-5,6,11,12-Tetrahydro-5,11- epoxydibenzo[a,e]cycloctene, an Analogue of Kagan's Ether

Preparation of 2,8-Dihydroxy-5,6,11,12-Tetrahydro-5,11- epoxydibenzo[a,e]cycloctene, an Analogue of Kagan's Ether

The Reimer-Tiemann Reaction.

TheCannizzaro Reaction

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