Zur Darstellung reinsten Eisessigs

Heß, Kurt; Haber, Heinz

doi:10.1002/cber.19370701107

Cited by 12 publications

(8 citation statements)

References 13 publications

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“…Silicon and titanium tetrachlorides react with acetic acid to give the chlorotriacetates M C l ( O A c ) 3 . These compounds react further with acetic acid to give binuclear products.…”

Section: Ternary System C U ( O a C ) 2 -N H 4 O A C -H O A C Atmentioning

confidence: 99%

“…Corresponding hydroxoacetates with the composition M 2 ( O H ) 3 ( O A c ) 3 •2HOAc gradually precipitate from the solution. Corresponding hydroxoacetates with the composition M 2 ( O H ) 3 ( O A c ) 3 •2HOAc gradually precipitate from the solution.…”

Section: Ternary System C U ( O a C ) 2 -N H 4 O A C -H O A C Atmentioning

confidence: 99%

“…No direct evidence for the presence of Pb 3 + species was obtained but the observed kinetics require its participation in the reaction. Cobalt(III) acetate, on the basis of transference experiments, seems to form Co(OAc) 2 + , Co(OAc) 3 and Co(OAc) 4 " species, while Go(II) acetate solutions contain Co(OAc) + , Co(OAc) 2 , Co(OAc) 3~, and Co(OAc) 4 2 " ions. Ion migration studies 194 show that lead (II) acetate solutions in acetic acid contain both positively and negatively charged species of Pb(II) and that the concentration of the former species is increased by the addition of water while the concentration of the latter is increased by the addition of the acetate ion.…”

Section: Oxidation-reduction Reactionsmentioning

confidence: 99%

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Anhydrous Acetic Acid as Nonaqueous Solvent

Popov

1970

The Chemistry of Nonaqueous Solvents

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“…Silicon and titanium tetrachlorides react with acetic acid to give the chlorotriacetates M C l ( O A c ) 3 . These compounds react further with acetic acid to give binuclear products.…”

Section: Ternary System C U ( O a C ) 2 -N H 4 O A C -H O A C Atmentioning

confidence: 99%

Section: Ternary System C U ( O a C ) 2 -N H 4 O A C -H O A C Atmentioning

confidence: 99%

Section: Oxidation-reduction Reactionsmentioning

confidence: 99%

See 1 more Smart Citation

Anhydrous Acetic Acid as Nonaqueous Solvent

Popov

1970

The Chemistry of Nonaqueous Solvents

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“…Riidorff (4) and Visser (5) state that 0.1% of water lowers the melting point of acetic acid by 0.2°. Pure acetic acid is stated by Hess and Haber (6) to melt at 16.625°( corr. ).…”

Section: Purification Of Materialsmentioning

confidence: 99%

The Bromination of Aliphatic Acids and Their Acyl Derivatives

Kharasch¹,

Hobbs²

1941

J. Org. Chem.

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Many studies of the reaction of bromine with aliphatic acids and with acyl derivatives have been recorded (1). The inconsistencies of data reported, and the conflicting conclusions drawn, however, indicate that a complete qualitative knowledge of factors governing bromination of these substances has not yet been attained. The nature and magnitude of the effects of recognized catalysts are inadequately known, in that some investigations have employed such relatively high2 "catalyst" concentrations as to suggest that the supposed catalysts might actually be primary reactants, and further in that the effects of light and oxygen (shown by previous studies in this laboratory (2) to be highly significant in other bromination reactions) have been neglected. The present study was designed to supplement existing knowledge of the effects of catalysts, with special attention to oxygen, and of the effect of light, and to test incidentally Watson's hypothesis that certain acid brominations take place through the intermediate acyl bromides. The authors hope that the data recorded may contribute towards a sounder basis for future quantitative studies.

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“…Though ramie still remains in the native form after heating for five days in water at 1500 C, partial conversion of hydrate cellulose into native cellulose takes place on heating for half an hour in water at 2000 C, and almost complete conversion after half an hour in glycerine at 2500 C (79). Native cellulose may also be recovered indirectly by way of the ammonia compound (80) or by way of alkali cellulose (81,79).…”

Section: Nucleic Acids and Nucleoproteinsmentioning

confidence: 99%

X-Ray Studies of the Structure of Compounds of Biological Interest

Astbury¹

1939

Annu. Rev. Biochem.

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Zur Darstellung reinsten Eisessigs

Cited by 12 publications

References 13 publications

Anhydrous Acetic Acid as Nonaqueous Solvent

Anhydrous Acetic Acid as Nonaqueous Solvent

The Bromination of Aliphatic Acids and Their Acyl Derivatives

X-Ray Studies of the Structure of Compounds of Biological Interest

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