Zum Chemischen Transport von ScNbO4 mit Cl2 und NbCl5/Cl2 Experimente und Modellrechnungen

Ross, R. R.; Gruehn, R.

doi:10.1002/zaac.19905910111

Cited by 11 publications

(1 citation statement)

References 34 publications

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“…Thus one can obtain transport rates and amounts of deposited condensed phases, e.g., for the following systems: Si/SiAs/I 2 /H 2 O, Si/SiAs/As/H 2 O, Ti/O/Hg/Cl, Ti/O/Te/Cl, VP/I 2 /H 2 , V 2 O 5 /NH 4 Cl/H 2 O, Cr 2 O 3 /CrOCl/Cl 2 /H 2 O, , Cr 2 O 3 /Br 2 /H 2 O, Cr 2 O 3 /CrBr 3 /Br 2 /H 2 O, Cr 2 O 3 /HgCl 2 /H 2 O, Cr 2 O 3 /CrI 3 /I 2 /H 2 O, CrP/CrI 2 /I 2 /H 2 , CrBr 3 /Br 2 /H 2 O, MnP/MnI 2 /I 2 /H 2 , CoP/CoI 2 /I 2 /H 2 , Mo/MoBr 2 /HgBr 2 /H 2 O, MoO 2 /Mo 4 O 11 /HgCl 2 /H 2 O, MoO 2 /Mo 4 O 11 /HgBr 2 /H 2 O, Eu/Al/Cl, W/WO 2 /HgBr 2 /H 2 O, WO 2 /HgCl 2 /H 2 O, WO 2 /HgBr 2 /H 2 O, , WO 2 /W 18 O 49 /HgI 2 /H 2 O, WO 3 /HgCl 2 /H 2 O, Rh 2 O 3 /RhCl 3 /Cl 2 /H 2 O, ScNbO 4 /Cl 2 /H 2 O, ScNbO 4 /NbCl 5 /Cl 2 /H 2 O, MnNb 2 O 6 /Cl 2 /H 2 O, MnNb 2 O 6 /NH 4 Cl/H 2 O, CoNb 2 O 6 /Cl 2 /H 2 O, CoNb 2 O 6 /NH 4 Cl/H 2 O, CoNb 2 O 6 /HgCl 2 /H 2 O, NiNb 2 O 6 /Cl 2 /H 2 O, NiNb 2 O 6 /NH 4 Cl/H 2 O, Ga 2 (SO 4 ) 3 /HCl/H 2 O, Ga 2 (SO 4 ) 3 /Cl 2 /H 2 O, In 2 (SO 4 ) 3 /HCl/H 2 O, FeSO 4 /NH 4 Cl/H 2 O, Fe 2 (SO 4 ) 3 /Cl 2 /H 2 O, Fe 2 (SO 4 ) 3 /HCl/H 2 O, Fe 2 (SO 4 ) 3 /NH 4 Cl/H 2 O, Cr 2 (SO 4 ) 3 /Cl 2 /H 2 O, and Cr 2 (SO 4 ) 3 /HCl/H 2 O …”

Section: The Cooperative Transport Modelunclassified

Developments in Measuring and Calculating Chemical Vapor Transport Phenomena Demonstrated on Cr, Mo, W, and Their Compounds

Lenz

Gruehn

1997

Chem. Rev.

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referred to but will not be discussed. The involvement of a hitherto unknown gaseous species may be indicated by the experimental data that do not agree with model calculations at all.We will report new possibilities of measuring the mass flux inside a closed ampule. The correlation of thermochemical calculations with experimental data is particularly proven in the systems containing Cr, Mo, W, or their compounds.

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Section: The Cooperative Transport Modelunclassified

Developments in Measuring and Calculating Chemical Vapor Transport Phenomena Demonstrated on Cr, Mo, W, and Their Compounds

Lenz

Gruehn

1997

Chem. Rev.

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Neues zum chemischen Transport als Methode zur Präparation und thermochemischen Untersuchung von Festkörpern

Gruehn

Glaum

2000

Angewandte Chemie

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Crystal growth experiments in the systems Ni₂MSbO₆ (M = Sc, In) using chemical vapour transport reactions: Ni₂InSbO₆ and NiSb₂O₆ crystals in the millimetre range

Weil

Mathieu

Nordblad

et al. 2013

Crystal Research and Technology

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Endothermic chemical vapour transport (CVT) reactions of Ni 2 MSbO 6 (M = Sc, In), using a temperature gradient T of 1313 → 1233 K and HgCl 2 , HgBr 2 , PtCl 2 or TeCl 4 as transport agents, led to growth of Ni 2 InSbO 6 single crystals in the millimetre range, whereas in the case of Ni 2 ScSbO 6 an incongruent dissolution of the solid in the source region was observed, leading to the formation of single crystals of the ternary phase NiSb 2 O 6 in the sink region. The crystal structures of the obtained crystals were refined from single crystal X-ray data with high precision [Ni 2 InSbO 6 : R3, Z = 3, a = 5.21640(10)Å, c = 14.0142(3)Å, 1279 structure factors, 33 parameters, R[F 2 > 2σ (F 2 )] = 0.0189; NiSb 2 O 6 : P4 2 /mnm, Z = 2, a = 4.63910(10)Å, c = 9.2182(2)Å, 500 structure factors, 19 parameters, R[F 2 > 2σ (F 2 )] = 0.0145]. Ni 2 InSbO 6 crystallizes in a corundum-related structure, NiSb 2 O 6 in the trirutile structure type. Spontaneous polarization and the ferroelectric transition temperature were estimated from the atomic arrangement and cation displacement along the polar axis in Ni 2 InSbO 6 . Magnetic measurements on Ni 2 InSbO 6 evidence an antiferromagnetic transition near T N = 74 K, with significant magnetic frustration.

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Zum Chemischen Transport von ScNbO₄ mit Cl₂ und NbCl₅/Cl₂ Experimente und Modellrechnungen

Cited by 11 publications

References 34 publications

Developments in Measuring and Calculating Chemical Vapor Transport Phenomena Demonstrated on Cr, Mo, W, and Their Compounds

Developments in Measuring and Calculating Chemical Vapor Transport Phenomena Demonstrated on Cr, Mo, W, and Their Compounds

Neues zum chemischen Transport als Methode zur Präparation und thermochemischen Untersuchung von Festkörpern

Crystal growth experiments in the systems Ni₂MSbO₆ (M = Sc, In) using chemical vapour transport reactions: Ni₂InSbO₆ and NiSb₂O₆ crystals in the millimetre range

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Zum Chemischen Transport von ScNbO4 mit Cl2 und NbCl5/Cl2 Experimente und Modellrechnungen

Cited by 11 publications

References 34 publications

Developments in Measuring and Calculating Chemical Vapor Transport Phenomena Demonstrated on Cr, Mo, W, and Their Compounds

Developments in Measuring and Calculating Chemical Vapor Transport Phenomena Demonstrated on Cr, Mo, W, and Their Compounds

Neues zum chemischen Transport als Methode zur Präparation und thermochemischen Untersuchung von Festkörpern

Crystal growth experiments in the systems Ni2MSbO6 (M = Sc, In) using chemical vapour transport reactions: Ni2InSbO6 and NiSb2O6 crystals in the millimetre range

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Product

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About

Zum Chemischen Transport von ScNbO₄ mit Cl₂ und NbCl₅/Cl₂ Experimente und Modellrechnungen

Crystal growth experiments in the systems Ni₂MSbO₆ (M = Sc, In) using chemical vapour transport reactions: Ni₂InSbO₆ and NiSb₂O₆ crystals in the millimetre range