“…Creation of homojunctions with p-type and n-type ZnO is difficult, however, because native donors in ZnO are known to compensate for holes. 2 Heterojunctions are a viable alternative, which can be fabricated using ZnO and another semiconducting material with a different bandgap (either n-type or p-type), such as Cu 2 O, [16][17][18][19] GaN, 3,7,24,25 Si, 4,5,8,[20][21][22][23]26 or SiC. 9,27,28 Although the epitaxial deposition of ZnO has been reported on many single crystal substrates, such as Au, 29,30 GaN, 31 InP, [32][33][34] MgAl 2 O 4 , 35 and sapphire, 10 the deposition on Si typically requires buffer layers.…”