Zinc incorporated covalent organic framework (Zn@DBPG): an efficient catalyst for the synthesis of carbamates through CO2 and non CO2 fixation pathways under sustainable condition

Recent Advances in the 3 d‐Transition‐Metal‐Catalyzed Synthesis of Isoquinolines and its Derivatives

“…Zinc salts and complexes have displayed broad applications in chemistry due to their abundance and important role in biological processes and properties such as low toxicity, high catalytic performance, and recyclability. Various zinc-catalyzed transformations have been reported in the literature, such as polymerization reaction, [110] oxidation, [111] CÀ H activation, [112] etc.…”

Light-Mediated Sustainable Conversion of Carbon Dioxide to Valuable Methanol by Highly Efficient Covalent Organic Framework g-C3N4 Composites as a Reusable Photocatalyst

“…To achieve this purpose, 196 countries have signed the Paris Agreement to reach zero-CO 2 emissions by 2050 . Mitigation of CO 2 in high-value commodity chemicals, for instances, , the epoxides, formamides, carboxylic acids, and the alternative fuels, methanol, is obviously a critical goal that would possess a positive impact on the global carbon balance. However, CO 2 being extremely stable and due to the high bond dissociation energy of CO (750 kJ/mol), it requires high temperature and pressure for thermocatalytic conversions .…”

Ionic liquid post-modified carboxylate-rich MOFs for efficient catalytic CO2 cycloaddition under solvent-free conditions

“…Post-synthetic modification (PSM) has become a common method for the functionalization of MOFs and is generally applied in MOF-catalyzed CO 2 epoxide addition reactions. 19,20 Ionic liquids (ILs) can be covalently bonded to MOFs to modify them, including enhancing the structural stability of the coordination polymer and introducing new functional groups. In a study conducted by Liu and coworkers, they discovered that a multi-functional MOF composite called MIL-101-IMBr could be prepared by modifying MIL-101 with imidazolium-based ILs.…”