Zinc bromide: a general mediator for the ionothermal synthesis of microporous polymers via cyclotrimerization reactions

Abstract

Conjugated microporous polymers (CMPs) are porous organic materials that display (semi)conducting behavior due to their highly π-conjugated structures, making them promising next-generation materials for applications requiring both electrical conductivity and...

Conjugated microporous polymers: their synthesis and potential applications in flexible electrodes

“…Cyclotrimerization usually requires heating of molten salts at temperatures above 300 °C to catalyze polymerization reactions. 73–75 In 2018, Baek et al 75 first reported that phosphorus pentoxide (P 2 O 5 ) catalyzes the direct condensation of aromatic amides to form covalent triazine-based frameworks (CTFs) (Fig. 8a).…”