Zeolite membrane separators for fire-safe Li-ion batteries – Effects of crystal shape and membrane pore structure

Murali, Dheeraj Ram Lingam; Banihashemi, Fateme; Lin, Jerry Y S

doi:10.1016/j.memsci.2023.121743

Cited by 8 publications

(3 citation statements)

References 55 publications

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“…By coating, membrane heat and puncture resistance can be significantly boosted, thereby reducing safety concerns related to rapid charging and heat dissipation, as well as thermal shrinkage of the membrane (leading to contact between anode and cathode), combustion, and explosion [ 75 ]. Currently, there are two prevailing coating types available, i.e., inorganic coatings and organic coatings [ 76 , 77 , 78 ]. Inorganic coating generally refers to the composite modification on the separator membrane with a layer of ceramic particles to enhance their comprehensive performance [ 79 ].…”

Section: Characteristics Outline Of Lib Separators and Polymeric Memb...mentioning

confidence: 99%

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Engineering Polymer-Based Porous Membrane for Sustainable Lithium-Ion Battery Separators

Li,

Duan

2023

Polymers

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Due to the growing demand for eco-friendly products, lithium-ion batteries (LIBs) have gained widespread attention as an energy storage solution. With the global demand for clean and sustainable energy, the social, economic, and environmental significance of LIBs is becoming more widely recognized. LIBs are composed of cathode and anode electrodes, electrolytes, and separators. Notably, the separator, a pivotal and indispensable component in LIBs that primarily consists of a porous membrane material, warrants significant research attention. Researchers have thus endeavored to develop innovative systems that enhance separator performance, fortify security measures, and address prevailing limitations. Herein, this review aims to furnish researchers with comprehensive content on battery separator membranes, encompassing performance requirements, functional parameters, manufacturing protocols, scientific progress, and overall performance evaluations. Specifically, it investigates the latest breakthroughs in porous membrane design, fabrication, modification, and optimization that employ various commonly used or emerging polymeric materials. Furthermore, the article offers insights into the future trajectory of polymer-based composite membranes for LIB applications and prospective challenges awaiting scientific exploration. The robust and durable membranes developed have shown superior efficacy across diverse applications. Consequently, these proposed concepts pave the way for a circular economy that curtails waste materials, lowers process costs, and mitigates the environmental footprint.

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Section: Characteristics Outline Of Lib Separators and Polymeric Memb...mentioning

confidence: 99%

“…ganic coatings and organic coatings [76][77][78]. Inorganic coating generally refers to the composite modification on the separator membrane with a layer of ceramic particles to enhance their comprehensive performance [79].…”

Section: Ideal Thermal Stability and Robust Shutdown Performancementioning

confidence: 99%

Engineering Polymer-Based Porous Membrane for Sustainable Lithium-Ion Battery Separators

Li,

Duan

2023

Polymers

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“…Recently, bis(fluorosulfonyl) imide, Li[(FSO 2 ) 2 N] (LiFSI, T tr > 200 °C), an imide family member, is attracting increasing interest, particularly for use as liquid electrolytes. This interest is driven by its well-defined properties, including no emission of hydrogen fluoride, low viscosity, high conductivity (>5 mS cm −1 ), and outstanding performance at both low and high temperatures, even under high rate conditions [ [35] , [36] , [37] , [38] , [39] ].…”

Section: Introductionmentioning

confidence: 99%

Thermal stability analysis of nitrile additives in LiFSI for lithium-ion batteries: An accelerating rate calorimetry study

Ali,

Park,

Raza

et al. 2024

Heliyon

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Electrode-supported high-tortuosity zeolite separator enabling fast-charging and dendrite-free lithium-ion/metal batteries

Rafiz,

Harika,

Lin

2023

Electrochimica Acta

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Zeolite membrane separators for fire-safe Li-ion batteries – Effects of crystal shape and membrane pore structure

Cited by 8 publications

References 55 publications

Engineering Polymer-Based Porous Membrane for Sustainable Lithium-Ion Battery Separators

Engineering Polymer-Based Porous Membrane for Sustainable Lithium-Ion Battery Separators

Thermal stability analysis of nitrile additives in LiFSI for lithium-ion batteries: An accelerating rate calorimetry study

Electrode-supported high-tortuosity zeolite separator enabling fast-charging and dendrite-free lithium-ion/metal batteries

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