2000
DOI: 10.1023/a:1009063106954
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Cited by 136 publications
(71 citation statements)
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“…The isomorphously T i substituted silicalite I structure TS-1 shows with H 2 O 2 a selective redox behavior in the selctive oxidation which can be used for the production of fine chemicals [45]. The transformation of this mechanism from pelletized catalysts to a catalytically active TS-1 membrane is under intense investigation.…”
Section: Isomorphous Substitution Of the Mfi Frameworkmentioning
confidence: 99%
“…The isomorphously T i substituted silicalite I structure TS-1 shows with H 2 O 2 a selective redox behavior in the selctive oxidation which can be used for the production of fine chemicals [45]. The transformation of this mechanism from pelletized catalysts to a catalytically active TS-1 membrane is under intense investigation.…”
Section: Isomorphous Substitution Of the Mfi Frameworkmentioning
confidence: 99%
“…The success of zeolites in second generation intermediary chemistry and fine chemicals [63][64][65][66][67][68][69][70][71][72][73] are on the whole, more recent [63-70, 72, 73] and benefit from the zeolitic materials developed mostly for the first two industries. Significant improvements of these materials are still possible, and new applications using new materials or not yet used so far, will be emerging in the coming decades.…”
Section: Openings For Zeolites In Refining and Petrochemicalsmentioning
confidence: 99%
“…In the synthesis of fine chemicals using zeolitic materials, it is often important to tune the acidÁbase strength of the catalyst with that of reactants and products in order to achieve optimal yields of products (23,24). The importance of acidÁbase pairs of the Na-X catalyst was investigated by modifying these pairs in the original Na-X catalyst by exchanging with a solution of ammonium acetate (see Experimental section for details).…”
Section: Resultsmentioning
confidence: 99%