The distinctive flavours of wines are affected by an enormous number of variables. However the grape variety and factors affecting wine development and berry composition exert major influences on distinctive flavours, whereas fermentation has very little overall effect. Although very little is known about specific compounds responsible for characteristic varietal flavours, in two cases compounds have been identified in grapes that are 'impact' compounds. In Muscat of Alexandria and other 'aromatic' varieties, terpenes contribute to the distinctive floral aromas; however, over 90% of the terpene content may occur as nonvolatile terpene glycosides, which can serve as flavour precursors. The amount of the bellpepper pyrazine, 2-methoxy-3-isobutylpyrazine, has recently been correlated with the intensity of 'vegetative' Sauvignon blanc and Cabernet Sauvignon wines. In both of these instances, the 'impact' compounds have been shown to respond to climatic and/or geographical influences. The effects of specific geographical, viticultural and enological variables on wine flavour has been examined in Cabernet Sauvignon wines using partial least squares regression.
IntroductionInvestigating compounds and factors that affect wine flavour is not unlike trying to piece together a jigsaw puzzle for which only few pieces are available. As for many systems, wine flavour is elicited by over 400 volatile compounds and an unquantified number of nonvolatile compounds. Quantitative and qualitative volatile data for many varieties of wines have been published, along with odour thresholds for these compounds and descriptions of their aromas in single-component systems. However, the flavour of complex systems, such as wines, cannot be predicted using additive models from information about single compounds in model systems. With a few exceptions, perceived flavour is the result of a pattern or specific ratios of many compounds, rather than being attributable to one 'impact' compound. Since so little is known about which compounds determine the varietal distinctiveness of wine aromas, at this stage, it is not