on the CeO 2 rich side, the four phases were determined to be Ba(Ce 1-z Y z ) O 3-x , BaY 2 CuO 5 , CuO x and CeO 2 . The Ba 2 YCu 3 O 6+x /CeO 2 reaction is limited by solid-state diffusion, and the reaction kinetics obey the parabolic rule, x = Kt 1/2 , where x = thickness of the reaction layer, t = time, and K = a constant related to the rate constant; K was determined to be 1.6 · 10 -3 lm/s 1/2 at 790°C and 4.7 · 10 -3 lm/s 1/2 at 830°C. The activation energy for the reaction was determined to be E act = 2.67 · 10 5 J/mol using the Arrhenius equation.