Zn
metal is thermodynamically unstable in aqueous electrolytes,
which induces dendrite growth and ongoing parasitic reactions at the
interface during the plating process and even during shelf time, resulting
in rapid battery failure and hindering the practical application of
aqueous Zn ion batteries. In this work, glycine, a common multifunctional
additive, is utilized to modulate the solvation shell structure and
enhance the interfacial stability to guard the reversibility and stability
of the Zn anode. Apart from partially replacing the original SO4
2– in the contact ion pair of Zn2+[H2O]5·OSO3
2– complexes to suppress the formation of Zn4(OH)6SO4·xH2O byproducts at
the interface, glycine molecules can also form a water-poor electrical
double layer on the zinc metal surface during resting and be further
reduced to build in situ a ZnS-rich solid electrolyte
interphase (SEI) layer during cycling, which further suppresses side
reactions and the random growth of Zn dendrites in the whole process.
As expected, the cycle life of the symmetrical cells reaches over
3200 h in glycine-containing electrolytes. In addition, the Zn//NVO
full cell shows exceptional cycling stability for 3000 cycles at 5
A g–1. Given the low-cost superiority of glycine,
the proposed strategy for interfacial chemistry modulation shows considerable
potential in promoting the commercialization progress of aqueous batteries.