Abstract:Fibre-reinforced composites were produced by the modification of the static horizontal Bridgman method. The single-crystalline composite matrix consisted of the tetragonal T phase (Al 72 Cu 27 Co 1 ). Decagonal quasicrystal D phase (Al 64 Cu 20 Co 16 ) was the reinforcement in the form of fibres parallel to the solidification direction. These fibres were surrounded by the tetragonal Θ phase (Al 66 Cu 31 Co 3 ). The composite specimens in the shape of plates were studied by tensile tests and X-ray topography. T… Show more
“…Specific contrast is also created for other defects that occurred in the single-crystalline materials. [13,23] The misorientation angle may be calculated using the shift value in the topograms. [13] The minimal misorientation angle, determined by X-ray topography method, is on the order of arc minutes, which are much lower than for the EBSD method.…”
Single-crystalline superalloy CMSX-4 is studied in the as-cast state and after heat treatment, with material being taken from turbine blade castings. The effect of the heat treatment on the defect structure of the root area near the selector/root connection is emphasized. Multiscale analysis is performed to correlate results obtained by X-ray topography and positron annihilation lifetime spectroscopy (PALS). Electron microscopy observations were also carried out to characterize the inhomogeneity in dendritic structure. The X-ray topography was used to compare defects of the misorientation nature, occurring in as-cast and treated states. The type and concentration of defects before and after heat treatment in different root areas were determined using the PALS method, which enables voids, mono-vacancies, and dislocations to be taken into account. In this way, differences in the concentration of defects caused by heat treatment are rationalized.
“…Specific contrast is also created for other defects that occurred in the single-crystalline materials. [13,23] The misorientation angle may be calculated using the shift value in the topograms. [13] The minimal misorientation angle, determined by X-ray topography method, is on the order of arc minutes, which are much lower than for the EBSD method.…”
Single-crystalline superalloy CMSX-4 is studied in the as-cast state and after heat treatment, with material being taken from turbine blade castings. The effect of the heat treatment on the defect structure of the root area near the selector/root connection is emphasized. Multiscale analysis is performed to correlate results obtained by X-ray topography and positron annihilation lifetime spectroscopy (PALS). Electron microscopy observations were also carried out to characterize the inhomogeneity in dendritic structure. The X-ray topography was used to compare defects of the misorientation nature, occurring in as-cast and treated states. The type and concentration of defects before and after heat treatment in different root areas were determined using the PALS method, which enables voids, mono-vacancies, and dislocations to be taken into account. In this way, differences in the concentration of defects caused by heat treatment are rationalized.
“…1. The measured diffraction angles of 2θ were recalculated in d-spacing and compared with data collected previously [11]. The TEM electron diffraction patterns were obtained from selected areas of the samples.…”
Microstructure of terminal area of Al65Cu32.9Co2.1ingots (numbers indicate at.%), obtained via directional solidification was studied. Scanning Electron Microscopy, Transmission Electron Microscopy and X-ray powder diffraction were applied. Point microanalysis by Scanning Electron Microscope was used for examination of chemical compositions of alloy phases. It was found that tetragonal θ phase of Al2Cu stoichiometric formula was the dominate phase (matrix). Additionally the alloy contained orthogonal set of nanofibres of Al7Cu2Co T phase with the average diameter of 50-500 nm and oval areas of hexagonal Al3(Cu,Co)2H-phase, surrounded by monoclinic AlCu η1phase rim. Inside some areas of H-phase cores of decagonal quasicrystalline D phase were observed.
“…The crystalquasicrystal (CQ) composites can be produced ex situ by powder metallurgy methods [2] or in situ by directional solidification [3]. In this paper the modified horizontal Bridgman method was used for obtaining CQ fibrous composite [4]. Due to specific atomic structure, decagonal aluminium based quasicrystal phases posses many useful anisotropic properties such as an anisotropic resistivity, magnetization and magnetoresistivity [5].…”
Composite based on Al–Cu–Co alloy obtained by directional solidification, were characterized. The quasicrystalline decagonal D phase of Al64Cu20Co16 was the reinforcement and the singlecrystalline tetragonal T phase of Al72Cu27Co1 was the matrix of the composite. The phases were identified by powder X-ray diffraction (XRD). The composite was analysed by light optical microscope and electron microscopes. The SEM and TEM techniques were used. Additionally the Laue method was used. The results of the study showed that the reinforcement has a form of parallel fibres of 20-40 μm diameter. Quasicrystal structure of fibres contained the phason strain. The quasicrystalline phase in the form of decagonal columns was also present inside composite pores.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.