Materials issues in III-V alloy semiconductors and our current understanding of degradation mechanism in III-V compound semiconductors and optical devices are systematically reviewed. Generation of defects and thermal instability are among these issues for these systems. In each phenomenon, generation mechanism of defects and structure are clarified. Three major degradation modes of optical devices, rapid degradation, gradual degradation, and catastrophic failure are briefly summarized, and the rapid and the gradual degradation modes are discussed in more detail.
Materials Issues in III-V Alloy SemiconductorsMaterials issues in the growth of III-V alloy semiconductor thin films are focused on (1). These include the generation of various kinds of defects during growth, the generation of modulated structures due to spinodal decomposition and atomic ordering associated with growth kinetics on the surface.
Defect generationDefect generation is one of the important materials issues in III-V alloy semiconductor thin film growth. Defects introduced during growth are classified into two types: interface defects and bulk defects.Interface defects. Defects belonging to this type are stacking faults, V-shaped dislocations, dislocation clusters, microtwins, inclusions, and misfit dislocations. Interface defects due to contamination, thermal damage of the substrate, local segregation at the interface, and those due to lattice-mismatch are schematically shown in Figs. 1 and 2.The stacking faults shown in Fig. 1(a) are generated from the hetero-interface, extending along the four equivalent {111} planes, forming a stacking fault tetrahedron (2). In MBE-grown crystals, they often correspond to surface defects (usually observed as "oval defects" lying along the <110> direction).Pair pits are often observed on the chemically etched surface of thin films. In the TEM image of the area which includes pair pits, small dislocation segments are observed. From the shape of the dislocations, this dislocation pair is assumed to comprise a Vshaped dislocation (see Fig. 1(b)). Occasionally, preferential etching takes place at such V-shaped dislocations (3).