X-ray diffraction, 31P NMR and europium photoluminescence properties of the Na2Ba1−xSrxMg(PO4)2 system related to the glaserite type structure

Boukhris, Amal; Glorieux, Benoît; Amara, Mongi Ben

doi:10.1016/j.molstruc.2014.11.063

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Cited by 3 publications

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“…Magnesium phosphates are of increasing interest because of their potential applications as host materials for optically active rare earth ions (Seo, 2013;Kim et al, 2013;Boukhris et al, 2015). Moreover, these materials are very attractive in terms of basic research because they exhibit a rich structural chemistry due to their polymorphism (Ait Benhamou et al, 2010;Orlova et al, 2015).…”

Section: Chemical Contextmentioning

confidence: 99%

Synthesis and crystal structure of a new magnesium phosphate Na₃RbMg₇(PO₄)₆

Hamed

Boukhris

Badri

et al. 2017

Acta Crystallogr E Cryst Commun

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Trisodium rubidium heptamagnesium hexakis(orthophosphate) exhibits a new structure type, with MgOx (x = 5 and 6) polyhedra linked directly to each other through common corners or edges and reinforced by corner-sharing with PO4 tetrahedra. The resulting anionic three-dimensional framework leads to the formation of channels in which the Na+ cations are located, while the Rb+ cations are located in large interstitial cavities.

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