“…Using the evolutionary computations of single stars of Maeder and Meynet (1987) and the average Mvi S -Tefr-spectral type-luminosity class calibration of TABLE I The actual mass of a star given its spectral type and luminosity class using the evolutionary tracks with CCO1; the numbers between brackets correspond to evolutionary tracks without CCO (Vanbeveren, 1987) Humphreys and McElroy (1984), Table I gives an average mass-spectral type-luminosity class relation for massive single stars and MCB components. The sample contains at least 4 binaries where observational evidence is present that mass transfer is going on, i.e., AO Cas (a contact system, Hilditch and Bell, 1987), 29 CMa (a semi-detached system with gas streams present, McCluskey et al, 1975), HD 149404 (the most evolved star, an O9Ia, is the less massive component, Massey and14 Cep (Hilditch, 1974). As a general rule it can be stated that non-evolved massive O-type binary components correspond to stars with initial ZAMS mass larger than 20 Mo, whereas the lower mass MCB components correspond to spectral type B0-B2 (V, IV, and III).…”