2021
DOI: 10.1177/09596836211041740
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Widely used charcoal analysis method in paleo studies involving NaOCl results in loss of charcoal formed below 400°C

Abstract: This study investigated the effects a dilute solution of bleach (4% sodium hypochlorite), has on charcoal. We were particularly interested in considering if charcoal formed under different conditions of pyrolysis was differentially affected by this treatment, which is commonly used for the quantification of charcoal in sediments. We first produced a series of charcoal samples, under laboratory conditions (at temperatures between 250°C and 800°C and under oxygen limited conditions) and then measured total surfa… Show more

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Cited by 15 publications
(5 citation statements)
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References 32 publications
(45 reference statements)
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“…CHAR values for both size fractions remain low through this interval (c. 5000–2000 cal years BP) showing an insensitivity of this proxy to low combustion temperature fires inferred from PAHs. Others have found that low-intensity fires are poorly represented in sedimentary charcoal records (Higuera et al, 2005), potentially as a function of methodological biases (Constantine and Mooney, 2021). The lack of response in CHAR values at our sites is also possibly a result of limited charcoal production and/or atmospheric transport from this type of burning in this environment, as lower temperature fires provide less convective energy to mobilize the dispersal of charcoal (Clark, 1988; Peters and Higuera, 2007; Vachula and Richter, 2018).…”
Section: Discussionmentioning
confidence: 99%
“…CHAR values for both size fractions remain low through this interval (c. 5000–2000 cal years BP) showing an insensitivity of this proxy to low combustion temperature fires inferred from PAHs. Others have found that low-intensity fires are poorly represented in sedimentary charcoal records (Higuera et al, 2005), potentially as a function of methodological biases (Constantine and Mooney, 2021). The lack of response in CHAR values at our sites is also possibly a result of limited charcoal production and/or atmospheric transport from this type of burning in this environment, as lower temperature fires provide less convective energy to mobilize the dispersal of charcoal (Clark, 1988; Peters and Higuera, 2007; Vachula and Richter, 2018).…”
Section: Discussionmentioning
confidence: 99%
“…They showed that low, medium and high temperature fires could be confidently inferred from FTIR spectra and used this to infer past fire intensity in Ecuador (Gosling et al 2019). Subsequent research has confirmed the ability of FTIR spectra to infer broad temperature ranges from charcoal particles from important plant species in South Africa and Australia (Constantine et al 2021). The FTIR spectra are not always easy to interpret due to the relatively poor preservation of charcoal produced at low temperatures and diagenic chemical processes within the sediment that can obscure the fire temperature signal.…”
Section: Fire Temperature Indicatorsmentioning
confidence: 95%
“…Sites (Table 1) were included based on their proximity to the study site (mainland south-eastern Australia) and only if they had a robust chronology (including at least one radiometric age ( 14 C or 210 Pb date) per 400 years and had age values encompassing the past 100 years). It should be noted that the composite charcoal record derived herein included data where charcoal was extracted using oxidant treatments, and thus may carry a partial bias towards higher intensity fires (Constantine and Mooney, 2022).…”
Section: Methodsmentioning
confidence: 99%
“…Analysis of past fire regimes in Australia has focused on the use of charcoal particles preserved within sedimentary archives. Extraction of these charcoal particles has relied on the use of light oxidants to extract charcoal from sediments, a process Constantine and Mooney (2022) have recently demonstrated can preferentially remove the less recalcitrant charcoal fraction produced at lower temperatures (e.g. low severity or intensity wildfires).…”
Section: Introductionmentioning
confidence: 99%