In this paper, Na2GdMg2(VO4)3:Yb3+,Er3+ phosphors were synthesized through highâtemperature solidâstate method. According to Xâray powder diffractogram, diffuse reflection spectra, scanning electron microscopy, upâconversion (UC) emission spectra, powerâdependent UC spectra, fluorescent lifetime curves, and temperatureâdependent emission spectra, the crystal structures, UC luminescent characteristics, and the performances of temperature sensing by using fluorescence intensity ratio technique were studied in detail. Heavyâdoped phosphors with 59% (Yb3+ and Er3+) doping content are achieved. In addition, excited by 980nm laser, three characteristic luminescence peaks of Er3+ at 525Â nm (2H11/2 â 4I15/2), 550Â nm (4S3/2 â 4I15/2) and 660Â nm (4F9/2 â 4I15/2) emerge in the UC spectra of Er3+ singleâdoped and Yb3+,Er3+ coâdoped phosphors. UC spectra are dominated by green emission and greatly enhanced UC emission over 389 times is realized by introducing Yb3+. In addition, the ratiometric techniques of thermally coupled energy levels of Er3+ (525/550Â nm, 2H11/2/4S3/2 â 4I15/2) are used to achieve a wide range of temperature measurement. When the temperature is 303Â K, relative sensitivity is as high as 0.976%Kâ1. The minimal temperature resolution is 0.3Â K@303Â K. All experimental results show Yb3+,Er3+ coâdoped Na2GdMg2(VO4)3 phosphors might act as optical temperature sensing materials.