Sweeping deposited particles is absolutely
essential in order to
maintain the excellent functionality of superhydrophobic surfaces.
Many methods have been proposed to sweep microparticles deposited
on tips of micro/nanostructures. However, how to sweep nanoparticles
trapped in cavities of superhydrophobic surfaces has remained an outstanding
issue. Here, we show that harnessing the reversible wetting transition
provides a feasible way to sweep such nanoparticles. Using molecular
dynamics simulations, we demonstrate that the electrically induced
CB–W wetting transition makes liquid intrude into a groove
and wet a trapped hydrophilic nanoparticle; however, once the electric
field is removed, a spontaneous W–CB dewetting transition happens,
and the extruded liquid transports the hydrophilic nanoparticle to
the groove top, successfully picking up the trapped hydrophilic nanoparticle.
We further find that the adhesion between the nanoparticle and groove
bottom wall hinders the successful pickup, and picking up such a nanoparticle
requires a stronger particle hydrophilicity. With the introduction
of amphiphilic Janus particles into a liquid, we exhibit that the
electrically induced reversible wetting transition can also successfully
pick up a trapped hydrophobic nanoparticle. By means of calculations
of the potential of mean force (PMF), we reveal pathways of both the
CB–W wetting transition and the W–CB dewetting transition
and hence answer why and how a hydrophilic or a hydrophobic nanoparticle
is picked up successfully.