Why Frankfurt Examples Beg the Question

Woodward, Philip

doi:10.1111/1467-9833.00156

Cited by 5 publications

(6 citation statements)

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“…Due to the commercial impact of this new pigment, the preparation protocol remained secret for almost 20 years until being revealed by Woodward in 1724 . In the same year, Brown performed the precipitation with other metallic hexacyanoferrates such as silver, mercury, copper, bismuth, and lead instead of iron.…”

Section: Hybrid Materials: When Serendipity Becomes Know‐howmentioning

confidence: 99%

History of Organic–Inorganic Hybrid Materials: Prehistory, Art, Science, and Advanced Applications

Faustini

Nicole

Ruiz‐Hitzky

et al. 2018

Adv Funct Materials

302

228

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The rise of organic-inorganic hybrid materials in both academia and industry results from a convergence of diverse expertise and communities and is driven by the curiosity of open-minded scientists. In this review article, a historical perception on the evolution of hybrid material science is described. The major periods associated with the genesis of hybrid materials are discussed: prebiotic hybrid chemistry, hybrid materials made through know-how, the rise of silicates and silicon chemistry, modern hybrids: a mushrooming multidisciplinary field of research, and current applications of hybrid materials fully integrated in the society. Finally, the review presents an outlook that summarizes some future prospects related to hybrid materials.

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Section: Hybrid Materials: When Serendipity Becomes Know‐howmentioning

confidence: 99%

History of Organic–Inorganic Hybrid Materials: Prehistory, Art, Science, and Advanced Applications

Faustini

Nicole

Ruiz‐Hitzky

et al. 2018

Adv Funct Materials

302

228

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“…The second agent could prevent the physical, external action carrying out the choice, but the act of will is free and undetermined even if the external behavior executing the choice is prevented. Although his argument against the Frankfurt examples is not precisely the one presented here, an article that overlaps somewhat with this argument is Woodward 2002.…”

mentioning

confidence: 71%

The Nature and Basis of Human Dignity

Lee¹,

George²

2008

Ratio Juris

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We argue that all human beings have a special type of dignity which is the basis for (1) the obligation all of us have not to kill them, (2) the obligation to take their well-being into account when we act, and (3) even the obligation to treat them as we would have them treat us, and indeed, that all human beings are equal in fundamental dignity. We give reasons to oppose the position that only some human beings, because of their possession of certain characteristics in addition to their humanity (for example, an immediately exercisable capacity for self-consciousness, or for rational deliberation), have full moral worth. What distinguishes human beings from other animals, what makes human beings persons rather than things, is their rational nature, and human beings are rational creatures by virtue of possessing natural capacities for conceptual thought, deliberation, and free choice, that is, the natural capacity to shape their own lives.

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“…Prussian blue (PB) pigment has got the distinction of being the first molecular coordination compounds (ferric ferrocyanide complex (Fe 4 [Fe(CN) 6 ] 3 ), which was discovered by the German artist Diesbach in 1703 . For about three centuries, it is used as important ingredient in the preparation of paints, printing inks, laundry dyes, etc. However, its structural, electronic, and magnetic properties and other transition metal analogues have been studied only in the past decade .…”

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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Prussian Blue/NaNO₂as an Efficient Reagent for the Nitration of Phenols in Aqueous Bisulfate and Acetonitrile Medium: Synthetic and Kinetic Study

Srinivas

Mathew

Rajanna

et al. 2017

Int. J. Chem. Kinet.

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The reaction kinetics of Prussian blue (PB)/NaNO2 initiated for the nitration of phenols by in aqueous bisulfate and acetonitrile medium indicated first‐order dependence on [phenol], [NaNO2], and [PB]. An increase in [KHSO4] accelerated the rate of nitration under otherwise similar conditions. The rate of nitration was faster in the solvent of higher dielectric constant (D). Observed results were in accordance with Amis and Kirkwood plots [log k′ vs. (1/D) and [(D − 1)/(2D + 1)]. These findings together with the linearity of plots, log k′ versus (vol% of acetonitrile (ACN)) and mole fraction of (nx) ACN, probably indicate the importance of both eloctrostatic and nonelctrostatic forces, solvent–solute interactions during nitration of phenols. Reaction rates accelerated with the introduction of electron‐donating groups and retarded with electron‐withdrawing groups, which are interpreted by Hammett's theory of linear free energy relationship. Hammett's reaction constant (ρ) is a fairly large negative (ρ < 0) value, indicating attack of an electrophile on the aromatic ring. Furthermore, an increase in temperature decreased the reaction constant (ρ) values. This trend was useful in obtaining isokinetic temperature (β) from Exner's plot of ρ versus 1/T. Observed β value (337.8 K) is above the experimental temperature range (303–323 K), indicating that the enthalpy factors are probably more important in controlling the reaction.

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Why Frankfurt Examples Beg the Question

Cited by 5 publications

References 0 publications

History of Organic–Inorganic Hybrid Materials: Prehistory, Art, Science, and Advanced Applications

History of Organic–Inorganic Hybrid Materials: Prehistory, Art, Science, and Advanced Applications

The Nature and Basis of Human Dignity

Prussian Blue/NaNO₂as an Efficient Reagent for the Nitration of Phenols in Aqueous Bisulfate and Acetonitrile Medium: Synthetic and Kinetic Study

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Why Frankfurt Examples Beg the Question

Cited by 5 publications

References 0 publications

History of Organic–Inorganic Hybrid Materials: Prehistory, Art, Science, and Advanced Applications

History of Organic–Inorganic Hybrid Materials: Prehistory, Art, Science, and Advanced Applications

The Nature and Basis of Human Dignity

Prussian Blue/NaNO2as an Efficient Reagent for the Nitration of Phenols in Aqueous Bisulfate and Acetonitrile Medium: Synthetic and Kinetic Study

Contact Info

Product

Resources

About

Prussian Blue/NaNO₂as an Efficient Reagent for the Nitration of Phenols in Aqueous Bisulfate and Acetonitrile Medium: Synthetic and Kinetic Study