In this study, gas metal arc welding (GMAW) was used to construct a thin wall structure in a layer-by-layer fashion using an AWS ER70S-6 electrode wire with the help of a robot. The Charpy impact test was performed after extracting samples in directions both parallel and perpendicular to the deposition direction. In this study, multiple factors related to the resulting absorbed energy have been discussed. Despite being a layered structure, homogeneous behavior with acceptable deviation was observed in the microstructure, hardness, and fracture toughness of the structure in both directions. The fracture is extremely ductile with a dimpled fibrous surface and secondary cracks. An estimate for fracture toughness based on Charpy impact absorbed energy is also given.