Volatile
organic compounds (VOCs) were measured in the Los Angeles
(LA) Basin from mid-April to mid-July 2020 during the COVID-19 pandemic,
as a part of the Los Angeles Air Quality Campaign (LAAQC). VOCs were
quantified in over 450 samples using one- and two-dimensional gas
chromatography with different detectors; mixing ratios were determined
for 150 compounds associated with on- and off-road mobile, volatile
chemical product, and biogenic sources. During the sampling period,
traffic counts increased from ∼55% to ∼80% of pre-COVID
levels. While the average afternoon combustion-derived VOCs and carbon
monoxide (CO) mixing ratios did not change significantly between April–May
and June–July, there was a shift in the distribution to higher
mixing ratios in June–July, particularly for VOCs associated
with gasoline evaporation. Compared to observations made in the last
major air quality campaign in the LA Basin (CalNex-2010), emission
ratios for 40 compounds relative to acetylene (VOC/acetylene) have
remained similar, while emission ratios relative to CO (VOC/CO) have
dropped to ∼60% of their 2010 values. This divergence in trends
suggests that whereas mobile sources are still the dominant source
of the combustion-derived VOCs measured in the LA Basin, there has
been a shift in the mobile source sectors, with a growing contribution
from sources that have lower CO/acetylene emission ratios, including
off-road equipment and vehicles. In addition to the observed shift
in source sector contributions, estimated OH exposure was 70–120%
higher than in 2010.