Wetting and reaction of BN-SiO2 ceramic by molten Ti-40Ni-20Nb (at.%) filler alloy

Yang, Jinghong; Zhang, L.X.; Sun, Zhirong; Feng, Ji

doi:10.1016/j.apsusc.2019.143912

Applied Surface Science

2020

DOI: 10.1016/j.apsusc.2019.143912

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Wetting and reaction of BN-SiO2 ceramic by molten Ti-40Ni-20Nb (at.%) filler alloy

Jinghong Yang

L.X. Zhang

Zhirong Sun

et al.

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Cited by 8 publications

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“…Brazing is a typical technology to make a tight connection between different solid parts. , Inspired by the whole integrity feature of the brazing structure, the brazing method is attractive for connecting a ceramic electrolyte and an Li anode. However, how do we realize this thought?…”

mentioning

confidence: 99%

Titanium–Oxygen Clusters Brazing Li with Li_6.5La₃Zr_1.5Ta_0.5O₁₂ for High-Performance All-Solid-State Li Batteries

Bai,

Zhao,

Yang

et al. 2023

Nano Lett.

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Garnet-based solid-state electrolytes are considered crucial candidates for solid-state Li batteries due to their high Li + conductivity and nonflammability; however, poor interfacial contact with the Li anode and growth of Li dendrites limit their application. Herein, a high-activity titanium− oxygen cluster is used as a brazing filler to braze the Li 6.5 La 3 Zr 1.5 Ta 0.5 O 12 (LLZTO) with an Li anode into the whole unit. The brazing layer leads to a significantly lower interfacial impedance of 8.32 Ω cm 2 . Furthermore, the brazing layer is an isotropic amorphous ion-electron hybrid conductive layer, which significantly promotes Li + transport and regulates the distribution of the electric field, therefore inhibiting the growth of Li dendrites. The cell exhibits an ultrahigh critical current density of 2.3 mA cm −2 and stable cycling of over 4000 h at 0.5 mA cm −2 (25 °C).

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mentioning

confidence: 99%

Titanium–Oxygen Clusters Brazing Li with Li_6.5La₃Zr_1.5Ta_0.5O₁₂ for High-Performance All-Solid-State Li Batteries

Bai,

Zhao,

Yang

et al. 2023

Nano Lett.

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Understanding the interfacial properties in BN-SiO2 diphase ceramic/TiNiNb filler alloy systems: First-principles and mechanical studies

Yang

Wei

Liu³

et al. 2021

Applied Surface Science

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Wetting and interfacial reaction of liquid CuAg-Ti alloy on SiO2-BN ceramic

Niu

Yang

Wang

et al. 2022

Applied Surface Science

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Wetting and reaction of BN-SiO2 ceramic by molten Ti-40Ni-20Nb (at.%) filler alloy

Cited by 8 publications

References 29 publications

Titanium–Oxygen Clusters Brazing Li with Li_6.5La₃Zr_1.5Ta_0.5O₁₂ for High-Performance All-Solid-State Li Batteries

Titanium–Oxygen Clusters Brazing Li with Li_6.5La₃Zr_1.5Ta_0.5O₁₂ for High-Performance All-Solid-State Li Batteries

Understanding the interfacial properties in BN-SiO2 diphase ceramic/TiNiNb filler alloy systems: First-principles and mechanical studies

Wetting and interfacial reaction of liquid CuAg-Ti alloy on SiO2-BN ceramic

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Wetting and reaction of BN-SiO2 ceramic by molten Ti-40Ni-20Nb (at.%) filler alloy

Cited by 8 publications

References 29 publications

Titanium–Oxygen Clusters Brazing Li with Li6.5La3Zr1.5Ta0.5O12 for High-Performance All-Solid-State Li Batteries

Titanium–Oxygen Clusters Brazing Li with Li6.5La3Zr1.5Ta0.5O12 for High-Performance All-Solid-State Li Batteries

Understanding the interfacial properties in BN-SiO2 diphase ceramic/TiNiNb filler alloy systems: First-principles and mechanical studies

Wetting and interfacial reaction of liquid CuAg-Ti alloy on SiO2-BN ceramic

Contact Info

Product

Resources

About

Titanium–Oxygen Clusters Brazing Li with Li_6.5La₃Zr_1.5Ta_0.5O₁₂ for High-Performance All-Solid-State Li Batteries

Titanium–Oxygen Clusters Brazing Li with Li_6.5La₃Zr_1.5Ta_0.5O₁₂ for High-Performance All-Solid-State Li Batteries