We
report on a spin filter effect that emerges at potential barriers
between a ≃10 nm thick magnetic surface layer and nonmagnetic
regions prepared at the surface of Li-doped ZnO microwires by low-energy
H+-ion implantation. The spin filter effect manifests in
a large positive magnetoresistance that persists to room temperature,
is linear in magnetic field, shows a maximum around 30 K, scales linearly
with the number of successive potential barriers created along the
microwires, and vanishes when the potential barrier is absent. The
specific features of the observed effect can be reproduced with a
model that describes a spin-polarized transport through a potential
barrier acting as a minority spin filter with an efficiency P
sf > 10% at room temperature and P
sf = 100% at 10 K.