Abstract:In this paper, we investigate weak Hopf algebras introduced in Li (J Algebra 208:72-100, 1998; Commun Math Phys 225:191-217, 2002) corresponding to quantum algebras U q ( f (K , H )) (see Wang et al. in Commun Algebra 30:2191-2211. A new class of algebras is defined, which is denoted by wU d q . For d = ((1, 1) | (1, 1)), denote wU d q briefly by w 1 U q ; for d = ((0, 0) | (0, 0)), denote wU d q briefly by w 2 U q . In some cases, the necessary and sufficient conditions for w 1 U q and w 2 U q to be weak H… Show more
“…Note that none of these bialgebras are Hopf algebras unless S is a group. Other more sophisticated examples are the weak quantized enveloping algebras of semisimple Lie algebras, generalized Kac-Moody algebras and superalgebras (see [1] and [6] for details).…”
Section: Examples 21 the Most Natural Examples Of Bialgebras With Weak Antipode Coming By Considering S A Finitementioning
In this paper we introduce the theory of multiplication alteration by two-cocycles for bialgebras with weak antipode. Moreover, by the connection between two-cocycles and invertible skew pairings, we show that a special case of the double cross product of these bialgebras can be obtained as a deformation of a bialgebra with weak antipode.
“…Note that none of these bialgebras are Hopf algebras unless S is a group. Other more sophisticated examples are the weak quantized enveloping algebras of semisimple Lie algebras, generalized Kac-Moody algebras and superalgebras (see [1] and [6] for details).…”
Section: Examples 21 the Most Natural Examples Of Bialgebras With Weak Antipode Coming By Considering S A Finitementioning
In this paper we introduce the theory of multiplication alteration by two-cocycles for bialgebras with weak antipode. Moreover, by the connection between two-cocycles and invertible skew pairings, we show that a special case of the double cross product of these bialgebras can be obtained as a deformation of a bialgebra with weak antipode.
“…With the exception of the Rh-catalyzed α-C−H hydroacylation of aldimines, 8−10 the metal is proposed to coordinate to the imine N donor, which promotes the selective activation of the βand γ-C−H bonds of the most sterically hindered carbonyl substituent (i.e., functionalization occurs at substituent trans to the directing group N-substituent, see Figure 1A). 8,11,12 Inspired by the reactivity of Cu-dependent monooxygenase/ peroxygenase enzymes, 13−16 our research laboratory has published a series of papers that describe the utilization of imine directing groups, Cu, and H 2 O 2 to perform the γ hydroxylation of sp 2 and sp 3 C−H bonds and the β hydroxylation of sp 3 C−H bonds (Figure 1B; Note: following literature precedents on Cu-directed hydroxylation reactions, we named the carbonyl of the ketone C α and the adjacent position C β ). 17−20 The selectivity of these Cu-promoted oxidations, which were initially developed by Schoënecker and co-workers for the selective oxidation of steroids 21 and have been applied to the total synthesis of complex molecules, 22−24 also relies on the formation of only one of the imine isomers in unsymmetrical substrates (e.g., cyclohexyl phenyl ketone 18 ), an issue that can be avoided in the hydroxylation of symmetrical substrates (e.g., symmetrical benzophenones 18 ).…”
Herein, we describe the regioselective functionalization of unsymmetrical ketones using imine directing groups, Cu, and H 2 O 2 . The C− H hydroxylation of the substrate−ligands derived from 2-substituted benzophenones occurred exclusively at the γ-position of the unsubstituted ring due to the formation of only one imine stereoisomer. Conversely, the imines derived from 4-substituted benzophenones produced E/Z mixtures that upon reacting with Cu and H 2 O 2 led to two γ-C−H hydroxylation products. Contrary to our initial hypothesis, the ratio of the hydroxylation products did not depend on the ratio of the E/Z isomers but on the electrophilicity of the reactive [LCuOOH] 1+ . A detailed mechanistic analysis suggests a fast isomerization of the imine substrate−ligand binding the CuOOH core before the rate-determining electrophilic aromatic hydroxylation. Varying the benzophenone substituents and/or introducing electrondonating and electron-withdrawing groups on the 4-position of pyridine of the directing group allowed for fine-tuning of the electrophilicity of the mononuclear [LCuOOH] 1+ to reach remarkable regioselectivities (up to 91:9 favoring the hydroxylation of the electron-rich arene ring). Lastly, we performed the C−H hydroxylation of alkyl aryl ketones, and like in the unsymmetrical benzophenones, the regioselectivity of the transformations (sp 3 vs sp 2 ) could be controlled by varying the electronics of the substrate and/or the directing group.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.