We Go Pogo

Soper, Kerry D.

doi:10.14325/mississippi/9781617032844.001.0001

Cited by 2 publications

(1 citation statement)

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“…Empty instrument (background) and empty capillary scans were run; all scans were collected over a ∼0.4 < Q < ∼26 Å -1 range. The raw data were processed using GudrunX 38,39,40 and over a 0.5 < Q < ∼20 Å -1 range and were corrected for background, container, absorption, multiple and Compton scattering. Fourier transformation of the processed total scattering data yielded real space pair distribution function, G(r).…”

Section: Pair Distribution Functionmentioning

confidence: 99%

Synthesis and characterisation of metal-organic framework-inorganic glass hybrid blends

Chester,

Castillo-Blas,

Sajzew

et al. 2023

Preprint

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Recently, increased attention has been focused on amorphous metal-organic frameworks (MOFs) and, more specifically, MOF glasses, the first new glass category discovered since the 1970s. In this work, we explore the fabrication of a compositional series of hybrid blends that combine ZIF-62(Zn) glass and an inorganic glass, 30Na2O-70P2O5, in an effort to combine the chemical versatility of the MOF glass with the mechanical properties of the inorganic glass. We investigate the interfacial interactions between the two components using pair distribution function analysis and solid state NMR spectroscopy, and suggest potential interactions between the two phases. Thermal analysis of the blend samples indicated that they were less thermally stable than the starting materials, and had a Tg shifted relative to the pristine materials. Annular dark field scanning transmission electron microscopy, X-ray energy dispersive spectroscopy (EDS), nanoindentation and 31P NMR all indicated close mixing of the two phases, suggesting that immiscible blends had formed.

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Section: Pair Distribution Functionmentioning

confidence: 99%