A multi-layered nanocomposite thin film was fabricated to increase the density of PbSe
quantum dots. It consisted of low-loss polymer layers and multi-stacked PbSe quantum dot
layers in series. The solutions of a UV-curable low-loss polymer and PbSe quantum dots
were spin-coated layer-by-layer. An arrayed and multi-stacked PbSe quantum dot layer was
self-assembled by spin-coating and solvent evaporation. The multi-stacked layers of PbSe
quantum dots have a face-centred cubic structure with an average {111} plane distance of
∼6.1 nm, determined by small-angle x-ray scattering. The average diameter of PbSe quantum dots is
∼5 nm and the average interparticle spacing distance is
∼2.5 nm,
characterized by transmission electron microscopy. The density of PbSe quantum dots in the single-arrayed
layer is ∼1.8 × 1012 cm−2
and the density in the three-layered thin film of multi-stacked PbSe QDs is
>1.6 × 1013 cm−2. The peak intensities of absorption and photoluminescence were increased with
increasing number of PbSe quantum dot layers. The time of luminescence decay to
e−1
is 138 ns at room temperature. We investigated the structures of multi-layered and
multi-stacked PbSe quantum dot thin films as well as their optical properties, and then
suggested their photonic applications.