We consider different hyperbolic systems of balance laws governing relativistic twospecies flows in mechanical equilibrium, but out of thermal equilibrium. Firstly, we focus on formulating explicit relaxation procedures that respect the second law of thermodynamics. Then, we prove that if a model M2 arises from a model M1 through a relaxation procedure, the hydrodynamical waves velocities λ are related by λ 2 M 2 λ 2 M 1 . The relaxation procedures we will consider are thermal relaxation and chemical relaxation.