For mid-wavelength infra-red (MWIR) modulation or detection applications, we propose α-Sn rich Ge/Ge 1-x Sn x /Ge a type-I single quantum wells (SQW) partially strain compensated on Ge 1-y Sn y relaxed layers grown onto (001)-oriented Ge substrate. Such elementary cells with W-like potential profiles of conduction and valence bands have been modeled by solving the one-dimensional Schrödinger equation under an applied external electrical field. First, strain effects on electrons, heavy holes (hh) and light holes (lh) energy bands for strained/relaxed Ge 1-x Sn x /Ge 1-y Sn y heterointerfaces are investigated using the modelsolid theory in the whole ranges (0 x, y 1) of Sn compositions. From the obtained band-discontinuities, band gaps and effective masses, Ge 1-y Sn y /Ge/Ge 0.80 Sn 0.20 /Ge/Ge 1-y Sn y cells are computed as a function of the Ge 0.80 Sn 0.20 well width for three compositions of the Ge 1-y Sn y buffer layer (y=0.05, 0.07 and 0.09) in order to get the optimum quantum confinement of electrons and holes levels while keeping a reasonable amount of averaged strain in the cell. The electric field effect on the absorption spectra is given. An absorption coefficient in the 6 to 3 10 3 cm −1 range is reasonably obtained for a SQW at room temperature with a rather large Stark shift of the direct transition between 0.46 and 0.38 eV (i.e., λ=3.26-2.70 μm) at large external fields (50 kV/cm). These characteristics are attractive for the design of MWIR optical modulators.