Water scarcity is an acute worldwide problem with increasing
frequency
even in the developed countries of Europe. Nature has inspired scientists
to carry out atmospheric water harvesting both from fog and dew on
surfaces of extreme wettability or biphilic surfaces (surfaces with
hydrophilic and hydrophobic patterns). Literature reports exhibit
large variation and contradictory results. Herein, we systematically
study the effect of the different biphilic shapes on both dew and
fog harvesting, clarifying the variable results observed in the literature.
First, we demonstrate a facile and scalable method of biphilic surface
fabrication using plasma micro-nanotexturing, plasma deposition, and
plasma etching through a stencil mask. We comparatively study the
water collection performance of three different biphilic pattern shapes
and two uniform patterns, in two different harvesting modes, namely,
dew harvesting and fog collection. Our results demonstrate superior
atmospheric water collection efficiency for biphilic patterns. We
demonstrate increased rate compared to untreated surfaces, 2×
for fog collection, and 1.6× for dew harvesting. We also demonstrate
that biphilic spot- and biphilic path-like patterns behave differently
depending on the harvesting mode: spot patterns show maximum water
collection in fog collection and minimum in dew harvesting, whereas
path-like patterns show maximum water collection in dew harvesting.