“…[11][12][13] Further advantages of combining CRP techniques with emulsion polymerization to produce industrially relevant (block)copolymers are obvious: Waterborne processes are not only cheap, they moreover provide efficient heat transfer, a low viscosity, and renounce volatile organic compounds, while coincidently giving rise to well-defined polymer architectures. [14][15][16] Several methods based on the RDRP mechanism have been developed, the most common ones being the atom transfer radical polymerization (ATRP), 17,18 nitroxide-mediated polymerization (NMP), 19 and RAFT polymerization. 20,21 Besides the conventional thermal initiation, these methods allow control through external physical (light irradiation, ultrasonication) [22][23][24][25] and chemical stimuli (metal-, redox-, enzyme-, Lewis acid-, or electrochemicallycatalyzed), [26][27][28][29][30] with light being lately one of the most prominent initiation sources.…”