“…However, all the doping elements considered in this study were indicated to reduce the LiPON crystal unit cell volume-but, interestingly, to increase the amorphous LiPON cell volume, indicating the ability of the dopants to enhance the Li ion conductivity. Lee et al reported that, in their experiments, doping Ti into amorphous LiPON enhanced Li + ionic conductivity, 17 quite consistent with our theoretical calculations on the effect of Tidoping on the ionic conductivity. However, due to the poor energetic stability of Ti-doped LiPON, compared to that of undoped LiPON, more rapid formation of secondary phases and worse cyclability (shorter lifetime) were expected.…”