“…31,32,34 If the blends are kept in the melt for a prolonged period of time, some transesterification, evidenced by modification of the melting behavior, takes place. 11,33 New signals have not been observed in the WAXD patterns; only overlapping of the crystalline peaks of the two polyesters has been found, and this suggests the formation of block copolymers. 33,34 In a certain composition range, fibers with outstanding properties can be achieved from blends of PTT and PET.…”
Section: Introductionmentioning
confidence: 98%
“…6 Like PET, 7 PTT crystallizes in a triclinic crystal structure, with the periodicity along the c axis containing two repeating units and the methylene groups being arranged in a highly contracted gauche-gauche con-formation. 2,8,9 Several articles have appeared recently in the literature concerning the physical properties of PTT, [10][11][12][13][14][15] such as its outstanding resilience, ability to rapidly crystallize, morphological structure, and fiber properties.…”
Section: Introductionmentioning
confidence: 99%
“…[27][28][29][30] Some articles concerning blends of PET and PTT have also been published in recent years. 11,[31][32][33][34][35][36][37][38] Evidence for miscibility restricted to amorphous regions is provided in all these articles, and the crystallization behavior and wide-angle X-ray diffraction (WAXD) patterns suggest that the pure PET and PTT components crystallize simultaneously to form their own crystalline entities; this means that the unit cells remain individually different even if they coexist in the same bundles or spherulites. 31,32,34 If the blends are kept in the melt for a prolonged period of time, some transesterification, evidenced by modification of the melting behavior, takes place.…”
We investigated the reactive melt blending of poly(ethylene terephthalate) (PET) and poly(trimethylene terephthalate) (PTT) in terms of the thermal properties and structural features of the resultant materials. Our main objectives were (1) to investigate the effects of the processing conditions on the nonisothermal melt crystallization and subsequent melting behavior of the blends and (2) to assess the effects of the blending time on the structural characteristics of the transreaction products with a fixed composition. The melting parameters (e.g., the melting temperature, melting enthalpy, and crystallization temperature) decreased with the mixing time; the crystallization behavior was strongly affected by the composition and blending time. Moreover, a significant role was played by the final temperature of the heating treatment; this meant that interchange reactions occurred during blending and continued during thermal analysis. The wide-angle X-ray diffraction patterns obtained under moderate blending conditions showed the presence of crystalline peaks of PET and PTT; however, the profiles became flatter after blending. This effect was more and more evident as the mixing time increased. Transesterification reactions between the polyesters due to longer blending times with an intermediate composition led to a new copolymer material characterized by its own diffraction profile and a reduced melting temperature. V C 2011 Wiley Periodicals, Inc. J Appl Polym Sci 122: [698][699][700][701][702][703][704][705] 2011
“…31,32,34 If the blends are kept in the melt for a prolonged period of time, some transesterification, evidenced by modification of the melting behavior, takes place. 11,33 New signals have not been observed in the WAXD patterns; only overlapping of the crystalline peaks of the two polyesters has been found, and this suggests the formation of block copolymers. 33,34 In a certain composition range, fibers with outstanding properties can be achieved from blends of PTT and PET.…”
Section: Introductionmentioning
confidence: 98%
“…6 Like PET, 7 PTT crystallizes in a triclinic crystal structure, with the periodicity along the c axis containing two repeating units and the methylene groups being arranged in a highly contracted gauche-gauche con-formation. 2,8,9 Several articles have appeared recently in the literature concerning the physical properties of PTT, [10][11][12][13][14][15] such as its outstanding resilience, ability to rapidly crystallize, morphological structure, and fiber properties.…”
Section: Introductionmentioning
confidence: 99%
“…[27][28][29][30] Some articles concerning blends of PET and PTT have also been published in recent years. 11,[31][32][33][34][35][36][37][38] Evidence for miscibility restricted to amorphous regions is provided in all these articles, and the crystallization behavior and wide-angle X-ray diffraction (WAXD) patterns suggest that the pure PET and PTT components crystallize simultaneously to form their own crystalline entities; this means that the unit cells remain individually different even if they coexist in the same bundles or spherulites. 31,32,34 If the blends are kept in the melt for a prolonged period of time, some transesterification, evidenced by modification of the melting behavior, takes place.…”
We investigated the reactive melt blending of poly(ethylene terephthalate) (PET) and poly(trimethylene terephthalate) (PTT) in terms of the thermal properties and structural features of the resultant materials. Our main objectives were (1) to investigate the effects of the processing conditions on the nonisothermal melt crystallization and subsequent melting behavior of the blends and (2) to assess the effects of the blending time on the structural characteristics of the transreaction products with a fixed composition. The melting parameters (e.g., the melting temperature, melting enthalpy, and crystallization temperature) decreased with the mixing time; the crystallization behavior was strongly affected by the composition and blending time. Moreover, a significant role was played by the final temperature of the heating treatment; this meant that interchange reactions occurred during blending and continued during thermal analysis. The wide-angle X-ray diffraction patterns obtained under moderate blending conditions showed the presence of crystalline peaks of PET and PTT; however, the profiles became flatter after blending. This effect was more and more evident as the mixing time increased. Transesterification reactions between the polyesters due to longer blending times with an intermediate composition led to a new copolymer material characterized by its own diffraction profile and a reduced melting temperature. V C 2011 Wiley Periodicals, Inc. J Appl Polym Sci 122: [698][699][700][701][702][703][704][705] 2011
“…Research on superabsorbents was initiated by the development of a starch-based superabsorbent, Superslurper, by the U.S. Department of Agriculture, Northern Regional Research Center, in the late 1960s. 1 Since then, modification of natural raw materials such as starch, 2 cellulose, 3,4 and protein 5 and direct synthesis from hydrophilic monomers such as acrylamide 6,7 and acrylic acid 8,9 with crosslinkers have been utilized to prepare superabsorbents.…”
“…They then evaluated dyeing properties (dye uptake, fastness), as well as undertaking optical microscopical analyses, X-ray birefringence analyses, mechanical tests and differential scanning calorimetry (DSC) analyses [41,42]. Dyeing of polypropylene in an aqueous system with a special dispersing agent has also been studied [43][44][45][46][47][48][49]. It was found that the dyestuffs for polypropylene fibres need to be much more hydrophobic than common disperse dyes for poly(ethylene terephthalate) fibre.…”
A series of 1,4‐bis(alkylamino)anthraquinone dyestuffs were applied for supercritical fluid dyeing of unmodified polypropylene fabric, which is known to be difficult to dye in a conventional aqueous system. A marked tendency was shown that the dyeability improved as the carbon number of alkyl substituents on the anthraquinone chromophore increased. By evaluating the build‐up curves of the dyestuff, it was found that the carbon number of optimum alkyl chain length for 1,4‐bis(alkylamino)anthraquinone was 8–12. From the relationship between the build‐up curve and the colour fastness, it was concluded that the upper limit of dyeing depth for good colour fastness was 40 mmol/kg of fibre.
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