Abstract. The nanometer-scale correlated pinning disorder filling channels between regular twin boundaries in the melt-textured (Nd,Eu,Gd)Ba 2 Cu 3 O y composite is studied. Aligned with regular twin boundaries but tightly packed on nm-scale, this pinning medium is capable to significantly enhance pinning performance at high magnetic fields. We show that oxygen annealing plays a principal role in the formation mechanism of this defect type. It seems that the nanoscale lamelar structure is extremely sensitive to the oxygenation procedure and to the terminal temperature.
IntroductionIn the LRE-Ba 2 Cu 3 O y compounds (LRE-123, LRE=light rare earth, Nd, Sm, Eu, Gd) much better vortex pinning environment can be created than in YBa 2 Cu 3 O y (Y-123) and thus they can carry significantly higher engineering currents [1][2][3]. Therefore, the LRE-123 bulks can trap the same magnetic field as Y-123 [4] but at higher temperatures or a higher magnetic field at the same temperature. It is commonly due to the additional source of point-like pins consisting of LRE/Ba solid solution nanometer scale clusters. Amount of this type of substitution is usually kept in an optimal range by growing the material in a reduced oxygen atmosphere [1][2][3] or by a slight excess of Cu over Ba in the starting powder [5]. This kind of pinning enhances mainly the secondary peak, the intermediate field range of J c -B dependence. The low-field part of it is usually increased by "large" particles of secondary phases (in the micron and sub-micron scales). The smaller the secondary phase particles size, the stronger is the effect [6,7]. In the case of nanometric nonsuperconducting particles the J c enhancement is so strong that extends up to intermediate fields and at high temperatures (where the secondary peak becomes weak) it passes over the whole field range up to the irreversibility field.In binary and ternary LRE-123 compounds variation in the mutual LRE ratio offers a natural tool how to manipulate with the local environment (say tensions) in the superconducting matrix. Due to different sizes of LRE ions their positions and concentrations are not exactly equivalent. It has been found that in a narrow range of the Nd:Eu:Gd ratio (around 33:38:28) the superconducting matrix is frustrated (in the positive sense from our point of view) so that a periodical correlated nanostructure appears [1]. It has either a zig-zag shape or, in the better case, it is planar, aligned with the regular twin boundaries and filling the channels between them. As the period of this new structure is typically a few nm, just in the range of the vortex core size, no wonder that a very strong pinning effect appears. This effect enhances critical currents at high magnetic fields and presents itself as a hump or shoulder