Von Benzoborirenen zu Benzoborol‐basierenden 1,2‐Diiminen und antiaromatischen Boroldiiden
Xiaocui Liu,
Myron Heinz,
Junyi Wang
et al.
Abstract:The reaction of benzoborirene with one equivalent of isocyanides leads to benzene‐fused boretes bearing one imine function, while the reaction with two equivalents of isocyanide affords 2,3‐dihydro‐2,3‐diiminoboroles with perfect regioselectivity. The isocyanide double insertion products represent a novel type of 1,2‐diimine with a benzoborole backbone. The reduction chemistry of the benzoborole‐supported 1,2‐diimine was investigated. Single‐ and two‐electron reduction allow for the isolation and full characte… Show more
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