The densities ðdÞ, velocities of sound ðvÞ, and surface tension ðcÞ, of anionic surfactant sodium dodecyl sulfate in presence of aqueous saccharides (fructose and maltose) with concentrations 0.01 and 0.10 mol kg -1 have been reported over a wide temperature range (293.15-313.15 K) at an interval of 5 K. The apparent molar volume ðu v Þ, isentropic compressibility ðj s Þ, and apparent molar adiabatic compression ðu j Þ values have been calculated using densities and velocities of sound data. Both, u v and u j vary non-linearly at lower concentration of surfactant and tend to achieve linearity at higher concentration of surfactant in presence of saccharides. From the surface tension data, parameters like surface excess ðC max Þ, minimum area occupied by the surfactant molecule at the saturated air/solution interface ðA min Þ and surface film pressure ðP CMC Þ have been computed. The effect of additives on these parameters has been discussed in terms of different types of the interactions pertaining in the micellar system. An attempt has also been made to draw an inference regarding the effect of these additives on the critical micelle concentration of the surfactant.