Volumetric properties of binary and ternary mixtures of diisopropyl ether, α,α,α-trifluorotoluene, 2,2,2-trifluoroethanol, and ethanol at a temperature 298.15K and pressure 101kPa

Prediction of thermophysical and transport properties of ternary organic non-electrolyte systems including water by polynomials

“…values of V E . It was shown 32 that for ternary system with fluorobenzene where the ternary contribution terms are higher, better results were obtained by the asymmetrical models, while for systems with TFE, 33 Ether + alcohol + hydrocarbon/ionic liquid. The ΔR of all binary system showed negative values.…”

Excess volumes, densities, speeds of sound and viscosities of binary systems of diisopropyl ether and acetates at 303.15K

“…[18]. Excess molar volumes of DIPE + a,a,atrifluorotoluene + fluorobenzene + ethanol + 2,2,2-trifluoroethanol, and of their ternary mixtures were measured [19,20]. Complex formation equilibria in binary mixtures of chloroform with dipropyl ether, diisopropyl ether, methyl tert-butyl ether, tetrahydrofuran, 1,4-dioxane, acetone, and methyl acetate were analyzed in detail using several association models [21].…”

Phase diagrams of (vapour+liquid) equilibrium for binary mixtures of α,α,α-trifluorotoluene with ethanol, or benzene, or chloroform at pressure 101.4kPa

“…Following previous studies devoted to the thermodynamic behaviour of liquid mixtures containing fluorinated hydrocarbons [1][2][3][4][5][6], we have measured the (vapour + liquid) equilibrium of binary mixtures of (ethanol + a,a,a-trifluorotoluene), (benzene + a,a,a-trifluorotoluene), and (chloroform + a,a,a-trifluorotoluene) at atmospheric pressure.…”

“…(x 1,az = 0.770, T az = 344.2 K)[6]. Whereas mixing is dominated by volumetric expansion with extreme excess volumes: fx 1 ðex:Þ ¼ 0:295; V E m ðex:Þ ¼ 0:279 cm 3 Á mol À1 g for {ethanol (1) + a,a,a-trifluorotoluene (2)}[1], and fx 1 ðex:Þ ¼ 0:428; V E m ðex:Þ ¼ 1:022 cm 3 Á mol À1 g for {chloro-form (1) + a,a,a-trifluorotoluene (2)}[13].…”