Voltammetric Determination of Rosmarinic Acid on Chitosan/Carbon Nanotube Composite-Modified Carbon Paste Electrode Covered with DNA

Mohamadi, Maryam; Mostafavi, Ali; Torkzadeh‐Mahani, Masoud

doi:10.1149/2.0581512jes

Cited by 22 publications

(21 citation statements)

References 39 publications

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“…The caffeic acid part is formed only from phenylalanine and the 3,4-dihydroxyphenyllactic acid only from tyrosine. [26][27][28] Rosmariic acid is a yellowish-white crystalline powder with a 174°C melting point, 29 an optical rotation of 140°, and D-(+) = (R)-(+) absolute configuration at the chiral center. 30 The compound is more soluble in most organic solvents, but less soluble in water.…”

Section: Chemistry Of Ramentioning

confidence: 99%

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Recent Advances in the Analysis of Rosmarinic Acid From Herbs in the Lamiaceae Family

Sik

Kapcsándi

Székelyhidi

et al. 2019

Natural Product Communications

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Rosmarinic acid (RA) is a phenolic acid found in a variety of plants, especially those in the Lamiaceae family. A number of biological effects are attributed to the compound; so, in recent years, RA has been the focus of many studies. The aim of this review is to provide information on the latest developments on flow chromatography analysis of RA. A reverse-phase high-performance liquid chromatography (HPLC) method with gradient elution and either diode array or mass spectrometric detection is usually used to measure the compound. Factors affecting the performance of HPLC analysis of RA such as sample preparation, column, mobile phase, and detection methods are discussed in detail in this review.

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Section: Chemistry Of Ramentioning

confidence: 99%

“…The caffeic acid part is formed only from phenylalanine and the 3,4-dihydroxyphenyllactic acid only from tyrosine. 26 -28…”

Section: Chemistry Of Ramentioning

confidence: 99%

Recent Advances in the Analysis of Rosmarinic Acid From Herbs in the Lamiaceae Family

Sik

Kapcsándi

Székelyhidi

et al. 2019

Natural Product Communications

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“…The prominent side of this novel method is its ability to simultaneously determine both RA and PCA with electrochemical technique; however, some electrodes have yielded more sensitivity, i. e., a lower detection limit, for individual analyte determination than that of this study. For instance, pretreated GCE , chitosan/carbon nanotube‐modified carbon paste electrode covered with DNA electrode , and pencil graphite electrode have been used in previous studies for individual RA determination with high sensitivity. However, the GCE/PoPD/Pt achieved a more sensitive RA detection than the system of carbon screen‐printed electrode modified with laccase‐immobilized indium tin oxide nanoparticles .…”

Section: Resultsmentioning

confidence: 99%

Simultaneous Determination of Rosmarinic Acid and Protocatechuic Acid at Poly(o‐Phenylenediamine)/Pt Nanoparticles Modified Glassy Carbon Electrode

Özdokur

Koçak

2019

Electroanalysis

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A system of Pt nanoparticles and poly(ortho‐phenylenediamine) film electrochemically deposited onto a glassy carbon electrode (GCE/PoPD/Pt) was fabricated. Scanning electron microscopy, Fourier‐transform infrared spectroscopy, and atomic force microscopy techniques were used to identify the surface characteristics of the composite electrode. The conductive polymers and Pt nanoparticles together resulted in a synergistic effect, and the new formed surface was highly active against polyphenolic structures. Rosmarinic acid (RA) and protocatechuic acid (PCA) are phenolic compounds found in plants, and they are used in many applications, particularly as pharmaceuticals. The GCE/PoPD/Pt was used for the simultaneous determination of RA and PCA in a pH 2.0 H2SO4 solution for the first time. The RA and PCA concentrations were determined using differential pulse voltammetry (DPV) and chronoamperometry. By the amperometry measurement, for RA and PCA, a linear relation was observed in the concentration ranges of 1–55 μmol L−1 and 1–60 μmol L−1, with detection limits of 0.5 μmol L−1 and 0.6 μmol L−1, respectively. In the simultaneous determination with DPV, the detection limits for both RA and PCA were calculated as 0.7 μmol L−1. The GCE/PoPD/Pt was successfully used for the simultaneous determination of RA and PCA in a real sample, and its accuracy was verified by high‐performance liquid chromatography studies.

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“…An electrochemical sensor based on a chitosan/carbon nanotube composite-modified carbon paste electrode covered with DNA has been prepared for the detection of rosmarinic acid (RA) [63]. More precisely, the bulk of a carbon paste electrode was modified with carbon nanotubes and chitosan and then the surface of the obtained electrode was covered with DNA.…”

Section: Phenolic Antioxidantsmentioning

confidence: 99%

Recent Advances in Electrochemical Chitosan-Based Chemosensors and Biosensors: Applications in Food Safety

Petrucci¹,

Pasquali²,

Scaramuzzo³

et al. 2021

Preprint

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Chitosan is a biopolymer derived from chitin. It is a non-toxic, biocompatible, bioactive, and biodegradable polymer. Due to its properties, chitosan has found applications in several and different fields such as agriculture, food industry, medicine, paper fabrication, textile industry, and water treatment. In addition to these properties, chitosan has a good film-forming ability which allows it to be widely used for the development of sensors and biosensors. This review is focused on the use of chitosan for the formulation of electrochemical chemosensors. It also aims to provide an overview of the advantages of using chitosan as an immobilization platform for biomolecules by highlighting its applications in electrochemical biosensors. Finally, applications of electro-chemical chitosan-based chemosensors and biosensors in food safety are illustrated

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Voltammetric Determination of Rosmarinic Acid on Chitosan/Carbon Nanotube Composite-Modified Carbon Paste Electrode Covered with DNA

Cited by 22 publications

References 39 publications

Recent Advances in the Analysis of Rosmarinic Acid From Herbs in the Lamiaceae Family

Recent Advances in the Analysis of Rosmarinic Acid From Herbs in the Lamiaceae Family

Simultaneous Determination of Rosmarinic Acid and Protocatechuic Acid at Poly(o‐Phenylenediamine)/Pt Nanoparticles Modified Glassy Carbon Electrode

Recent Advances in Electrochemical Chitosan-Based Chemosensors and Biosensors: Applications in Food Safety

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