2024
DOI: 10.1002/ange.202404930
|View full text |Cite
|
Sign up to set email alerts
|

Vollständig anorganische sp‐Kettenliganden: Isoelektronische B/N‐Analoga von E. O. Fischers Alkinylcarbinen

Luis Walther,
Krzysztof Radacki,
Rian D. Dewhurst
et al.

Abstract: Borylation of a tungsten‐bound N2 ligand and halide abstraction provides access to a cationic complex with an unprecedented linear NNBR ligand. This complex undergoes [3+2] cycloaddition with azides, and an unexpected chain‐extension reaction with an iminoborane, leading to a complex with a five‐atom B/N chain. These two [NNBR]‐containing complexes, inorganic analogues of E. O. Fischer's alkynylcarbynes, are very rare examples of molecules containing all‐inorganic chains of sp‐hybridized atoms.

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

0
0
0

Publication Types

Select...

Relationship

0
0

Authors

Journals

citations
Cited by 0 publications
references
References 53 publications
0
0
0
Order By: Relevance

No citations

Set email alert for when this publication receives citations?